256439

4,4′-Methylenebis(phenyl isocyanate)

98%

Manufacturer: Sigma Aldrich

CAS Number: 101-68-8

Synonym(S): 4,4′-MDI, Bis(4-isocyanatophenyl)methane

Select a Size

Pack Size SKU Availability Price
50 G 256439-50-G In Stock ₹ 2,533.05
500 G 256439-500-G In Stock ₹ 5,347.55
5 KG 256439-5-KG In Stock ₹ 38,104.00

256439 - 50 G

₹ 2,533.05

In Stock

Quantity

1

Base Price: ₹ 2,533.05

GST (18%): ₹ 455.949

Total Price: ₹ 2,988.999

Quality Level

200

Assay

98%

form

solid

reaction suitability

reagent type: cross-linking reagent

bp

200 °C/5 mmHg (lit.)

mp

42-45 °C (lit.)

density

1.18 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

O=C=Nc1ccc(Cc2ccc(cc2)N=C=O)cc1

InChI

1S/C15H10N2O2/c18-10-16-14-5-1-12(2-6-14)9-13-3-7-15(8-4-13)17-11-19/h1-8H,9H2

Other Options

Image Product Name Manufacturer Price Range
33428
4,4′-MDI
Supelco ₹ 8,053.80
AI66073
101-68-8 | BENZENE, 1,1'-METHYLENEBIS[4-ISOCYANATO-
A2B Chem ₹ 1,540.08 - ₹ 3,593.52

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Description

  • General description: 4,4′-Methylenebis(phenyl isocyanate) (MDI) is an aromatic diisocyanates class of monomer that is widely used in the production of polyurethane plastics, foam insulation, coatings, adhesives, and sealants. It is highly reactive due to the presence of two isocyanate functional groups. MDI is known for its excellent strength, durability, and resistance to chemical and environmental damage, which makes it useful in resin composition, lithographic printing plates, coating films, optical films, image display devices, semiconductor devices, and polyurethane foam production.
  • Application: 4,4′-Methylenebis(phenyl isocyanate) can be used as a starting material to synthesize: Polyurethane cationomers, that are applicable in medical implants.[1]A prepolymer for preparing self-healable polyurethane elastomers.[2] It can also be used as a cross-linking agent to synthesize PEBA (polyether-block-amide) copolymer with improved mechanical properties, which are mainly used in soles, medical tubes, aerospace parts, and chemical separation. Additionally, MDI is also used as a crosslinker to covalently modify graphene oxide (GO) and enhance the corrosion resistance of polystyrene coatings. The resultant polystyrene/GO-MDI composite coatings showed superior corrosion resistance to unmodified polystyrene coatings. This approach can potentially be used to improve the durability of materials in various industrial and biomedical applications.[3][4]

SAFETY INFORMATION

Pictograms

GHS08,GHS07

Signal Word

Danger

Hazard Statements

H315,H317,H319,H332,H334,H335,H351,H373

Precautionary Statements

P202 - P260 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Acute Tox. 4 Inhalation - Carc. 2 - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Inhalation - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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256439

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Quality Level:
200

Assay:
98%

form:
solid

reaction suitability:
reagent type: cross-linking reagent

bp:
200 °C/5 mmHg (lit.)

mp:
42-45 °C (lit.)

density:
1.18 g/mL at 25 °C (lit.)

storage temp.:
−20°C

SMILES string:
O=C=Nc1ccc(Cc2ccc(cc2)N=C=O)cc1

InChI:
1S/C15H10N2O2/c18-10-16-14-5-1-12(2-6-14)9-13-3-7-15(8-4-13)17-11-19/h1-8H,9H2

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Assay:
≥97.0% (HPLC)

form:
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bp:
__

mp:
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density:
__

storage temp.:
−20°C

SMILES string:
Cc1c(C)c(c(C)c2CCC(C)(C)Oc12)S(Cl)(=O)=O

InChI:
1S/C14H19ClO3S/c1-8-9(2)13(19(15,16)17)10(3)11-6-7-14(4,5)18-12(8)11/h6-7H2,1-5H3

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reaction suitability:
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bp:
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mp:
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density:
2.88 g/mL at 20 °C (lit.)

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SMILES string:
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256560

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bp:
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mp:
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0.691 g/mL at 25 °C (lit.)

storage temp.:
__

SMILES string:
CCCC#C

InChI:
1S/C5H8/c1-3-5-4-2/h1H,4-5H2,2H3