8.41799

Calcium hypochlorite

for synthesis

Manufacturer: Sigma Aldrich

CAS Number: 7778-54-3

Synonym(S): Calcium hypochlorite

Select a Size

Pack Size SKU Availability Price
100 G 8.41799-100-G In Stock ₹ 3,830.01
500 G 8.41799-500-G In Stock ₹ 4,760.00

8.41799 - 100 G

₹ 3,830.01

In Stock

Quantity

1

Base Price: ₹ 3,830.01

GST (18%): ₹ 689.402

Total Price: ₹ 4,519.412

Quality Level

200

form

tablet

potency

850 mg/kg LD50, oral (Rat)>2000 mg/kg LD50, skin (Rabbit)

mp

100 °C

density

2.35 g/cm3 at 20 °C

storage temp.

15-25°C

InChI

1S/Ca.2ClO/c;2*1-2/q+2;2*-1

InChI key

ZKQDCIXGCQPQNV-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-188-1182
Sigma Aldrich Fine Chemicals Biosciences Calcium hypochlorite technical grade | 7778-54-3 | MFCD00010900 | 1KG
Sigma Aldrich Fine Chemicals Biosciences ₹ 16,665.38
50-188-1183
Sigma Aldrich Fine Chemicals Biosciences Calcium hypochlorite technical grade | 7778-54-3 | MFCD00010900 | 250G
Sigma Aldrich Fine Chemicals Biosciences ₹ 8,111.09
211389
Calcium hypochlorite
Sigma Aldrich ₹ 2,316.55 - ₹ 6,191.90
211389
Calcium hypochlorite
Sigma Aldrich ₹ 2,316.55 - ₹ 6,191.90

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Description

  • General description: Calcium hypochlorite [Ca(OCl)2] is a stable oxidizing agent used for the conversion of ethers to esters; thioethers to sulfoxides; aldehydes to acids and alkenes to chlorohydrins. It is also used in the C-C bond cleavage and chlorination reactions.[1]
  • Application: Calcium hypochlorite can be used as an oxidative agent: In the epoxidation of various alkene derivatives.[2] To synthesize α-arylamino-α′-chloropropan-2-ones from various trifluoroacetyl-protected N-(2-chloroallyl)anilines via oxidative hydrolysis.[3] To convert 1o & 2o alcohols, α-hydroxyamides, and α-hydroxyesters to their corresponding aldehydes, ketones, α-ketoamides, and α-ketoesters in the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) as a catalyst.[4] To prepare dihydrotriazolediones and bis-dihydrotriazolediones by oxidation of urazoles and bis-urazoles.[5]
  • Analysis Note: Assay (iodometric): 67.0 - 75.0 %Identity: passes test

SAFETY INFORMATION

Pictograms

GHS03,GHS05,GHS07,GHS09

Signal Word

Danger

Hazard Statements

H272 - H302 - H314 - H400

Precautionary Statements

P210 - P260 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

Supplementary Hazards

EUH031

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 2

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850 mg/kg LD50, oral (Rat)>2000 mg/kg LD50, skin (Rabbit)

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15-25°C

InChI:
1S/Ca.2ClO/c;2*1-2/q+2;2*-1

InChI key:
ZKQDCIXGCQPQNV-UHFFFAOYSA-N

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InChI:
1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3

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COIOYMYWGDAQPM-UHFFFAOYSA-N

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InChI:
1S/C17H12O4/c1-10-14(18)12-8-5-9-13(17(19)20)16(12)21-15(10)11-6-3-2-4-7-11/h2-9H,1H3,(H,19,20)

InChI key:
KMMBBZOSQNLLMN-UHFFFAOYSA-N