187437
Bis(trimethylsilyl)acetylene
99%
Manufacturer: Sigma Aldrich
CAS Number: 14630-40-1
Synonym(S): BTMSA
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 10 G | 187437-10-G | In Stock | ₹ 6,614.08 |
| 50 G | 187437-50-G | In Stock | ₹ 24,886.68 |
187437 - 10 G
In Stock
Quantity
1
Base Price: ₹ 6,614.08
GST (18%): ₹ 1,190.534
Total Price: ₹ 7,804.614
Quality Level
100
Assay
99%
refractive index
n20/D 1.427 (lit.)
bp
136-137 °C (lit.)
mp
21-24 °C (lit.)
density
0.752 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C[Si](C)(C)C#C[Si](C)(C)C
InChI
1S/C8H18Si2/c1-9(2,3)7-8-10(4,5)6/h1-6H3
InChI key
ZDWYFWIBTZJGOR-UHFFFAOYSA-N
Related Products
Description
- General description: Bis(trimethylsilyl)acetylene (BTMSA) participates as nucleophile in Friedel-Crafts type acylations and alkylations. BTMSA undergoes rhodium catalyzed addition reaction with diarylacetylenes.[1] It undergoes cycloaddition with 1,5-hexadiynes in the presence of CpCo(CO)2 (Cp=cyclopentadienyl) to form benzocyclobutenes.[2] Structure of BTMSA was characterized by a centre of inversion present on triple bond (length=1.208(3)Å).[3] TiCl4-Et2AlCl catalyzed Diels-Alder reaction of BTMSA with norbornadiene has been reported.[4]
- Application: Bis(trimethylsilyl)acetylene (BTMSA) was used as starting reagent in the synthesis of functionalized 4-R-1,2-bis(trimethylsilyl)benzenes[5]. It was also used in the synthesis of (+)-brasilenyne[6] and (β-diketanato)Ag(BTMSA)[6].
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
35.6 °F
Flash Point(C)
2 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 99%
refractive index: n20/D 1.427 (lit.)
bp: 136-137 °C (lit.)
mp: 21-24 °C (lit.)
density: 0.752 g/mL at 25 °C (lit.)
storage temp.: 2-8°C
SMILES string: C[Si](C)(C)C#C[Si](C)(C)C
InChI: 1S/C8H18Si2/c1-9(2,3)7-8-10(4,5)6/h1-6H3
InChI key: ZDWYFWIBTZJGOR-UHFFFAOYSA-N
Quality Level:
100
Assay:
99%
refractive index:
n20/D 1.427 (lit.)
bp:
136-137 °C (lit.)
mp:
21-24 °C (lit.)
density:
0.752 g/mL at 25 °C (lit.)
storage temp.:
2-8°C
SMILES string:
C[Si](C)(C)C#C[Si](C)(C)C
InChI:
1S/C8H18Si2/c1-9(2,3)7-8-10(4,5)6/h1-6H3
InChI key:
ZDWYFWIBTZJGOR-UHFFFAOYSA-N
Quality Level: 100
Assay: 99%
refractive index: n20/D 1.560 (lit.)
bp: 142-143 °C/21 mmHg (lit.)
mp: 15-17 °C
density: 1.462 g/mL at 25 °C (lit.)
storage temp.: __
SMILES string: ClC(=O)c1c(Cl)cccc1Cl
InChI: 1S/C7H3Cl3O/c8-4-2-1-3-5(9)6(4)7(10)11/h1-3H
InChI key: JBLIDPPHFGWTKU-UHFFFAOYSA-N
Quality Level:
100
Assay:
99%
refractive index:
n20/D 1.560 (lit.)
bp:
142-143 °C/21 mmHg (lit.)
mp:
15-17 °C
density:
1.462 g/mL at 25 °C (lit.)
storage temp.:
__
SMILES string:
ClC(=O)c1c(Cl)cccc1Cl
InChI:
1S/C7H3Cl3O/c8-4-2-1-3-5(9)6(4)7(10)11/h1-3H
InChI key:
JBLIDPPHFGWTKU-UHFFFAOYSA-N
Quality Level: 100
Assay: 97%
refractive index: n20/D 1.444 (lit.)
bp: 273 °C (lit.)
mp: __
density: 1.021 g/mL at 25 °C (lit.)
storage temp.: __
SMILES string: __
InChI: 1S/C9H20O4/c1-4-8(10)12-6-7(3)13-9(11)5-2/h7-11H,4-6H2,1-3H3
InChI key: SNAJJYBUNRAGEF-UHFFFAOYSA-N
Quality Level:
100
Assay:
97%
refractive index:
n20/D 1.444 (lit.)
bp:
273 °C (lit.)
mp:
__
density:
1.021 g/mL at 25 °C (lit.)
storage temp.:
__
SMILES string:
__
InChI:
1S/C9H20O4/c1-4-8(10)12-6-7(3)13-9(11)5-2/h7-11H,4-6H2,1-3H3
InChI key:
SNAJJYBUNRAGEF-UHFFFAOYSA-N
Quality Level: 100
Assay: ≥99%
refractive index: n20/D 1.478 (lit.)
bp: __
mp: __
density: 0.886 g/mL at 25 °C (lit.)
storage temp.: __
SMILES string: C[C@]12C[C@@H]3C[C@H](C1)C[C@@](C)(C3)C2
InChI: 1S/C12H20/c1-11-4-9-3-10(5-11)7-12(2,6-9)8-11/h9-10H,3-8H2,1-2H3/t9-,10+,11-,12+
InChI key: CWNOIUTVJRWADX-BKUVIOGVSA-N
Quality Level:
100
Assay:
≥99%
refractive index:
n20/D 1.478 (lit.)
bp:
__
mp:
__
density:
0.886 g/mL at 25 °C (lit.)
storage temp.:
__
SMILES string:
C[C@]12C[C@@H]3C[C@H](C1)C[C@@](C)(C3)C2
InChI:
1S/C12H20/c1-11-4-9-3-10(5-11)7-12(2,6-9)8-11/h9-10H,3-8H2,1-2H3/t9-,10+,11-,12+
InChI key:
CWNOIUTVJRWADX-BKUVIOGVSA-N