379670

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane

Manufacturer: Sigma Aldrich

CAS Number: 95464-05-4

Synonym(S): Pd(dppf)Cl2 · CH2Cl2, Pd(dppf)Cl2 · DCM, [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1)

Select a Size

Pack Size SKU Availability Price
IND823-1G 379670-IND823-1G In Stock ₹ 4,580.00
1 G 379670-1-G In Stock ₹ 5,420.00
5 G 379670-5-G In Stock ₹ 17,190.00
IND823-5G 379670-IND823-5G In Stock ₹ 24,250.00
25 G 379670-25-G In Stock ₹ 83,782.80
250 G 379670-250-G In Stock ₹ 4,81,684.50

379670 - IND823-1G

₹ 4,580.00

In Stock

Quantity

1

Base Price: ₹ 4,580.00

GST (18%): ₹ 824.40

Total Price: ₹ 5,404.40

form

solid

Quality Level

200

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp

275-280 °C

SMILES string

[Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-14H;1H2;2*1H;;/q;;;;;;+2/p-2

InChI key

CWHRHCATIKFSND-UHFFFAOYSA-L

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Description

  • Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions
  • Analysis Note: Catalyst employed in the borylation of aryl halides with Bis(pinacolato)diboron(473294) as well as the coupling of the derived arylboronic esters with aryl halides leading to biaryls.[1] Also used in the synthesis of lactams by CO insertion[2] and medium-ring aryl ethers by intramolecular coupling of an aryl halide with an alcohol.[3]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332 - H315 - H319 - H335

Precautionary Statements

P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Compare Similar Items

Show Difference

Img

Sigma Aldrich

379670

--


form:
solid

Quality Level:
200

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp:
275-280 °C

SMILES string:
[Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI:
1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-14H;1H2;2*1H;;/q;;;;;;+2/p-2

InChI key:
CWHRHCATIKFSND-UHFFFAOYSA-L

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3797018

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Fischer Scientific

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TheC. DIFF QUIK CHEK COMPLETE™test ...


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Fischer Scientific

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Sterile kits provide room temperatu...


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