235040

1-Phenyl-1-trimethylsiloxyethylene

98%

Manufacturer: Sigma Aldrich

CAS Number: 13735-81-4

Synonym(S): α-(Trimethylsiloxy)styrene, Acetophenone enol trimethylsilyl ether

Select a Size

Pack Size SKU Availability Price
5 G 235040-5-G In Stock ₹ 5,910.45
25 G 235040-25-G In Stock ₹ 21,303.60

235040 - 5 G

₹ 5,910.45

In Stock

Quantity

1

Base Price: ₹ 5,910.45

GST (18%): ₹ 1,063.881

Total Price: ₹ 6,974.331

vapor density

>1 (vs air)

Quality Level

100

Assay

98%

form

liquid

refractive index

n20/D 1.502 (lit.)

bp

88-89 °C/11 mmHg (lit.)

density

0.938 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)OC(=C)c1ccccc1

InChI

1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3

Other Options

Image Product Name Manufacturer Price Range
50-241-8701
eMolecules​ Ambeed / Trimethyl[(1-phenylvinyl)oxy]silane / 1g / 552759186 / A844696 / / 13735-81-4 / MFCD00008582 / 192.333 / C11H16OSi
eMolecules​ ₹ 2,065.42
CS-0127818
Trimethyl((1-phenylvinyl)oxy)silane
ChemScene ₹ 1,625.64 - ₹ 27,036.96
AB58698
13735-81-4 | 1-Phenyl-1-trimethylsiloxyethylene
A2B Chem ₹ 427.80 - ₹ 5,219.16

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Description

  • General description: 1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran[1]. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants[2].
  • Application: 1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:β-amino ketones in water via Mannich-type reaction[3]cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction[4]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

235040

98%...


vapor density:
>1 (vs air)

Quality Level:
100

Assay:
98%

form:
liquid

refractive index:
n20/D 1.502 (lit.)

bp:
88-89 °C/11 mmHg (lit.)

density:
0.938 g/mL at 25 °C (lit.)

storage temp.:
2-8°C

SMILES string:
C[Si](C)(C)OC(=C)c1ccccc1

InChI:
1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3

Img

Sigma Aldrich

235067

99%...


vapor density:
__

Quality Level:
200

Assay:
99%

form:
liquid

refractive index:
n20/D 1.43 (lit.)

bp:
142-144 °C (lit.)

density:
0.898 g/mL at 25 °C (lit.)

storage temp.:
__

SMILES string:
CC[Si](Cl)(CC)CC

InChI:
1S/C6H15ClSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3

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Sigma Aldrich

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vapor density:
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100

Assay:
95%

form:
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refractive index:
__

bp:
__

density:
__

storage temp.:
__

SMILES string:
C[Si](C)(C)N([Na])[Si](C)(C)C

InChI:
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

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Sigma Aldrich

235083

95%...


vapor density:
__

Quality Level:
100

Assay:
95%

form:
__

refractive index:
__

bp:
__

density:
__

storage temp.:
__

SMILES string:
C[Si](C)(C)N([Na])[Si](C)(C)C

InChI:
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1