281239

Diallyl carbonate

99%

Manufacturer: Sigma Aldrich

CAS Number: 15022-08-9

Synonym(S): bis(prop-2-enyl) carbonate

Select a Size

Pack Size SKU Availability Price
5 G 281239-5-G In Stock ₹ 5,780.55
25 G 281239-25-G In Stock ₹ 24,323.78

281239 - 5 G

₹ 5,780.55

In Stock

Quantity

1

Base Price: ₹ 5,780.55

GST (18%): ₹ 1,040.499

Total Price: ₹ 6,821.049

Quality Level

100

Assay

99%

form

liquid

refractive index

n20/D 1.428 (lit.)

bp

95-97 °C/60 mmHg (lit.)

density

0.991 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C=CCOC(=O)OCC=C

InChI

1S/C7H10O3/c1-3-5-9-7(8)10-6-4-2/h3-4H,1-2,5-6H2

InChI key

JKJWYKGYGWOAHT-UHFFFAOYSA-N

Description

  • General description: Diallyl carbonate is an acrylating agent. Allyl carbonates are widely employed in Tsuji-Trost allylation, generating carbanion, boronate, phosphide, amide and alkoxide, nucleophiles in situ and improving reaction rates over allyl acetate. Allyl carbonates are also of considerable interest for the intramolecular decarboxylative assymetric couplings.
  • Application: Transesterification of diallyl carbonate with glycerol in the presence of a catalyst (Pd/PPh3), generates glycerol carbonate.

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319,H335

Precautionary Statements

P210 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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form:
liquid

refractive index:
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bp:
95-97 °C/60 mmHg (lit.)

density:
0.991 g/mL at 25 °C (lit.)

storage temp.:
2-8°C

SMILES string:
C=CCOC(=O)OCC=C

InChI:
1S/C7H10O3/c1-3-5-9-7(8)10-6-4-2/h3-4H,1-2,5-6H2

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JKJWYKGYGWOAHT-UHFFFAOYSA-N

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OC(=O)c1cc(O)c2ccccc2c1O

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1S/C11H8O4/c12-9-5-8(11(14)15)10(13)7-4-2-1-3-6(7)9/h1-5,12-13H,(H,14,15)

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