360058

(Triphenylsilyl)acetylene

98%

Manufacturer: Sigma Aldrich

CAS Number: 6229-00-1

Synonym(S): 1,1′,1′′-(Ethynylsilylidyne)tris[benzene], Ethynyltriphenylsilane, Triphenylsilylacetylene, Triphenylsilylethyne

Select a Size

Pack Size SKU Availability Price
5 G 360058-5-G In Stock ₹ 13,890.00

360058 - 5 G

₹ 13,890.00

In Stock

Quantity

1

Base Price: ₹ 13,890.00

GST (18%): ₹ 2,500.20

Total Price: ₹ 16,390.20

Quality Level

100

Assay

98%

mp

48-50 °C (lit.)

SMILES string

C#C[Si](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C20H16Si/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20/h1,3-17H

InChI key

WADKYPSVXRWORK-UHFFFAOYSA-N

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Description

  • General description: (Triphenylsilyl)acetylene is a terminal alkyne. Rhodium-catalyzed asymmetric addition of (triphenylsilyl)acetylene to diphenylphosphinylallene is reported.[1]
  • Application: (Triphenylsilyl)acetylene may be used in the synthesis of:selenothioic acid S-alkyl esters[2]methyl 2-(di{ 3, 5-bis[(triphenylsilyl)ethynyl]phenyl}-phosphino)benzoate[3]2-(di{3,5-bis[(triphenylsilyl)ethynyl]phenyl}-phosphino)benzoic acid[3]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
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Assay:
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mp:
48-50 °C (lit.)

SMILES string:
C#C[Si](c1ccccc1)(c2ccccc2)c3ccccc3

InChI:
1S/C20H16Si/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20/h1,3-17H

InChI key:
WADKYPSVXRWORK-UHFFFAOYSA-N

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1S/2BrH.Mg/h2*1H;/q;;+2/p-2

InChI key:
OTCKOJUMXQWKQG-UHFFFAOYSA-L

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O.N[C@@H](Cc1ccc(cc1)[N+]([O-])=O)C(O)=O

InChI:
1S/C9H10N2O4.H2O/c10-8(9(12)13)5-6-1-3-7(4-2-6)11(14)15;/h1-4,8H,5,10H2,(H,12,13);1H2/t8-;/m0./s1

InChI key:
OLZDHJRNUIXKLU-QRPNPIFTSA-N