520160

Shi Epoxidation Diketal Catalyst

98%

Manufacturer: Sigma Aldrich

CAS Number: 18422-53-2

Synonym(S): 1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose

Select a Size

Pack Size SKU Availability Price
5 G 520160-5-G In Stock ₹ 19,268.50

520160 - 5 G

₹ 19,268.50

In Stock

Quantity

1

Base Price: ₹ 19,268.50

GST (18%): ₹ 3,468.33

Total Price: ₹ 22,736.83

Quality Level

100

Assay

98%

optical activity

[α]20/D −120.9°, c = 1 in chloroform

greener alternative product characteristics

CatalysisLearn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

102-104 °C (lit.)

greener alternative category

, Aligned

SMILES string

CC1(C)O[C@@H]2CO[C@]3(COC(C)(C)O3)C(=O)[C@@H]2O1

InChI

1S/C12H18O6/c1-10(2)15-6-12(18-10)9(13)8-7(5-14-12)16-11(3,4)17-8/h7-8H,5-6H2,1-4H3/t7-,8-,12+/m1/s1

InChI key

IVWWFWFVSWOTLP-RWYTXXIDSA-N

Other Options

Image Product Name Manufacturer Price Range
50-174-2041
Sigma Aldrich Fine Chemicals Biosciences Shi Epoxidation Diketal Catalyst 98% | 18422-53-2 | MFCD11865369 | 5G
Sigma Aldrich Fine Chemicals Biosciences ₹ 24,002.15
CS-W016736
(3a'R,4S,7a'R)-2,2,2',2'-Tetramethyldihydrospiro[[1,3]dioxolane-4,6'-[1,3]dioxolo[4,5-c]pyran]-7'(4'H)-one
ChemScene ₹ 855.60 - ₹ 43,036.68
AB57037
18422-53-2 | 1,2:4,5-Di-O-Isopropylidene-Beta-D-Erythro-2,3-Hexodiulo-2,6-Pyranose
A2B Chem ₹ 598.92 - ₹ 9,753.84

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Description

  • General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
  • Application: Highly selective and active organocatalyst for the asymmetric epoxidation of alkenes with hydrogen peroxide. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline's reagent guide.An Efficient Catalytic Asymmetric Epoxidation MethodUse of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

520160

98%...


Quality Level:
100

Assay:
98%

optical activity:
[α]20/D −120.9°, c = 1 in chloroform

greener alternative product characteristics:
CatalysisLearn more about the Principles of Green Chemistry.

sustainability:
Greener Alternative Product

mp:
102-104 °C (lit.)

greener alternative category:
, Aligned

SMILES string:
CC1(C)O[C@@H]2CO[C@]3(COC(C)(C)O3)C(=O)[C@@H]2O1

InChI:
1S/C12H18O6/c1-10(2)15-6-12(18-10)9(13)8-7(5-14-12)16-11(3,4)17-8/h7-8H,5-6H2,1-4H3/t7-,8-,12+/m1/s1

InChI key:
IVWWFWFVSWOTLP-RWYTXXIDSA-N

Img

Supelco

52017

analytical standard...


Quality Level:
__

Assay:
≥98.0% (GC)

optical activity:
__

greener alternative product characteristics:
__

sustainability:
__

mp:
__

greener alternative category:
__

SMILES string:
CC(O)CC(O)=O

InChI:
1S/C4H8O3/c1-3(5)2-4(6)7/h3,5H,2H2,1H3,(H,6,7)

InChI key:
WHBMMWSBFZVSSR-UHFFFAOYSA-N

Img

Sigma Aldrich

520179

powder...


Quality Level:
__

Assay:
__

optical activity:
__

greener alternative product characteristics:
__

sustainability:
__

mp:
__

greener alternative category:
__

SMILES string:
O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O

InChI:
1S/6Al.2O2Si.9O/c;;;;;;2*1-3-2;;;;;;;;;

InChI key:
KZHJGOXRZJKJNY-UHFFFAOYSA-N

Img

Sigma Aldrich

520209

powder...


Quality Level:
100

Assay:
__

optical activity:
__

greener alternative product characteristics:
__

sustainability:
__

mp:
__

greener alternative category:
__

SMILES string:
O=[Al]O[Ti](=O)O[Al]=O

InChI:
1S/2Al.5O.Ti

InChI key:
CNRZQDQNVUKEJG-UHFFFAOYSA-N