900399

SLAP N-Bn Pip Reagent

95%

Manufacturer: Sigma Aldrich

CAS Number: 1908469-38-4

Synonym(S): N1-Benzyl-N1-((trimethylsilyl)methyl)ethane-1,2-diamine

Select a Size

Pack Size SKU Availability Price
500 MG 900399-500-MG In Stock ₹ 11,258.00

900399 - 500 MG

₹ 11,258.00

In Stock

Quantity

1

Base Price: ₹ 11,258.00

GST (18%): ₹ 2,026.44

Total Price: ₹ 13,284.44

Quality Level

100

Assay

95%

form

liquid (paste)

refractive index

n/D 1.5071

density

0.9366 g/mL

storage temp.

−20°C

Other Options

Image Product Name Manufacturer Price Range
CS-0645750
(2-Aminoethyl)(benzyl)[(trimethylsilyl)methyl]amine
ChemScene ₹ 1,17,816.12 - ₹ 9,00,262.32
AI82108
1908469-38-4 | (2-Aminoethyl)(benzyl)[(trimethylsilyl)methyl]amine
A2B Chem ₹ 21,390.00 - ₹ 75,635.04

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Description

  • Application: Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6 (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.
  • Other Notes: Technology Spotlight: SLAP Reagents for Piperazine SynthesisSilicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and KetonesLewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

198.0 °F

Flash Point(C)

92.2 °C

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−20°C

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