902489
Tris(trimethylsilyl)silanol
≥95%
Manufacturer: Sigma Aldrich
CAS Number: 7428-60-6
Synonym(S): (Hydroxy-bis(trimethylsilyl)silyl)-trimethylsilane, (TMS)3SiOH, 1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)trisilan-2-ol, Supersilanol
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 902489-1-G | In Stock | ₹ 21,411.85 |
| 5 G | 902489-5-G | In Stock | ₹ 67,764.50 |
902489 - 1 G
In Stock
Quantity
1
Base Price: ₹ 21,411.85
GST (18%): ₹ 3,854.133
Total Price: ₹ 25,265.983
Assay
≥95%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
refractive index
n/D 1.496
density
0.859 g/mL
InChI
1S/C9H28OSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h10H,1-9H3
InChI key
ABTWCNHNRLMBFR-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Hydroxy-tris(trimethylsilyl)silane | ChemScene | ₹ 10,352.76 | |
 | 7428-60-6 | 2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- | A2B Chem | ₹ 7,529.28 |
Related Products
Description
- Application: Under a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225).
- Other Notes: A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
200.3 °F
Flash Point(C)
93.5 °C
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Assay: ≥95%
form: liquid
reaction suitability: reaction type: C-C Bond Formation
refractive index: n/D 1.496
density: 0.859 g/mL
InChI: 1S/C9H28OSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h10H,1-9H3
InChI key: ABTWCNHNRLMBFR-UHFFFAOYSA-N
Assay:
≥95%
form:
liquid
reaction suitability:
reaction type: C-C Bond Formation
refractive index:
n/D 1.496
density:
0.859 g/mL
InChI:
1S/C9H28OSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h10H,1-9H3
InChI key:
ABTWCNHNRLMBFR-UHFFFAOYSA-N
Assay: ≥99.9%
form: powder
reaction suitability: __
refractive index: __
density: __
InChI: 1S/C81H68N4O8/c1-86-65-29-9-53(10-30-65)82(54-11-31-66(87-2)32-12-54)61-25-45-73-74-46-26-62(83(55-13-33-67(88-3)34-14-55)56-15-35-68(89-4)36-16-56)50-78(74)81(77(73)49-61)79-51-63(84(57-17-37-69(90-5)38-18-57)58-19-39-70(91-6)40-20-58)27-47-75(79)76-48-28-64(52-80(76)81)85(59-21-41-71(92-7)42-22-59)60-23-43-72(93-8)44-24-60/h9-52H,1-8H3
InChI key: XDXWNHPWWKGTKO-UHFFFAOYSA-N
Assay:
≥99.9%
form:
powder
reaction suitability:
__
refractive index:
__
density:
__
InChI:
1S/C81H68N4O8/c1-86-65-29-9-53(10-30-65)82(54-11-31-66(87-2)32-12-54)61-25-45-73-74-46-26-62(83(55-13-33-67(88-3)34-14-55)56-15-35-68(89-4)36-16-56)50-78(74)81(77(73)49-61)79-51-63(84(57-17-37-69(90-5)38-18-57)58-19-39-70(91-6)40-20-58)27-47-75(79)76-48-28-64(52-80(76)81)85(59-21-41-71(92-7)42-22-59)60-23-43-72(93-8)44-24-60/h9-52H,1-8H3
InChI key:
XDXWNHPWWKGTKO-UHFFFAOYSA-N
Assay: __
form: crystals
reaction suitability: reaction type: Fmoc solid-phase peptide synthesis
refractive index: __
density: __
InChI: __
InChI key: __
Assay:
__
form:
crystals
reaction suitability:
reaction type: Fmoc solid-phase peptide synthesis
refractive index:
__
density:
__
InChI:
__
InChI key:
__
Assay: __
form: liquid
reaction suitability: reaction type: Pegylationsreagent type: cross-linking reagent
refractive index: n/D 1.4641
density: 1.1395 g/mL
InChI: __
InChI key: __
Assay:
__
form:
liquid
reaction suitability:
reaction type: Pegylationsreagent type: cross-linking reagent
refractive index:
n/D 1.4641
density:
1.1395 g/mL
InChI:
__
InChI key:
__