415642
Ethyl phenylphosphinate
94%
Manufacturer: Sigma Aldrich
CAS Number: 2511-09-3
Synonym(S): Ethoxyphenylphosphine oxide, O-Ethyl phenylphosphinate, Phenylphosphinic acid ethyl ester
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 ML | 415642-5-ML | In Stock | ₹ 6,126.95 |
| 25 ML | 415642-25-ML | In Stock | ₹ 17,125.15 |
415642 - 5 ML
In Stock
Quantity
1
Base Price: ₹ 6,126.95
GST (18%): ₹ 1,102.851
Total Price: ₹ 7,229.801
Quality Level
100
Assay
94%
form
liquid
refractive index
n20/D 1.526 (lit.)
bp
94-95 °C/1 mmHg (lit.)
density
1.129 g/mL at 25 °C (lit.)
SMILES string
CCO[PH](=O)c1ccccc1
InChI
1S/C8H11O2P/c1-2-10-11(9)8-6-4-3-5-7-8/h3-7,11H,2H2,1H3
InChI key
UNUJZVUJPIOMGH-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences Ethyl phenylphosphinate | 2511-09-3 | MFCD11505905 | 5 mL | Sigma Aldrich Fine Chemicals Biosciences | ₹ 7,811.63 | |
 | Sigma Aldrich Fine Chemicals Biosciences Ethyl phenylphosphinate 94% | Purity: 94% | Mol Wt: 170.15 | 2511-09-3 | MFCD11505905 | 25ML | Sigma Aldrich Fine Chemicals Biosciences | ₹ 27,146.48 | |
 | Ethyl phenylphosphinate | ChemScene | ₹ 1,368.96 - ₹ 79,485.24 |
Description
- General description: Ethyl phenylphosphinate is an organophosphorous compound. It undergoes regioselective Markovnikov addition reaction with terminal alkynes in the presence of palladium-1,2-bis(diphenylphosphino)ethane complex (catalyst).[1] Ethyl phenylphosphinate is the photodecomposition product of Inezin (S-benzyl O-ethyl phenylphosphonothiolate) on the ultraviolet irradiation.[2] It can be prepared by the reaction of phosphinic acid with ethyl chloroformate in the presence of pyridine.[3] Its ethylation using ethyl trimethylsilyl phenylphosphonite or the corresponding trimethylstannyl ester has been described. Its free-radical addition to ethylene has been reported to proceed with the retention of configuration.[4]
- Application: Ethyl phenylphosphinate may be used in the preparation of the following diethyl imidazol-2-yl-(amino) methylphosphonates and phosphinates:[5]imidazol-2-yl-methyl(N-butylamino)phosphonate diethyl esterimidazol-2-yl-methyl(N-benzylamino)phosphonate diethyl esterimidazol-2-yl-methyl(N-butylamino)phenylphosphinate ethyl esterimidazol-2-yl-methyl(N-benzylamino)phenylphosphinate ethyl ester
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 94%
form: liquid
refractive index: n20/D 1.526 (lit.)
bp: 94-95 °C/1 mmHg (lit.)
density: 1.129 g/mL at 25 °C (lit.)
SMILES string: CCO[PH](=O)c1ccccc1
InChI: 1S/C8H11O2P/c1-2-10-11(9)8-6-4-3-5-7-8/h3-7,11H,2H2,1H3
InChI key: UNUJZVUJPIOMGH-UHFFFAOYSA-N
Quality Level:
100
Assay:
94%
form:
liquid
refractive index:
n20/D 1.526 (lit.)
bp:
94-95 °C/1 mmHg (lit.)
density:
1.129 g/mL at 25 °C (lit.)
SMILES string:
CCO[PH](=O)c1ccccc1
InChI:
1S/C8H11O2P/c1-2-10-11(9)8-6-4-3-5-7-8/h3-7,11H,2H2,1H3
InChI key:
UNUJZVUJPIOMGH-UHFFFAOYSA-N
Quality Level: __
Assay: 95%
form: liquid
refractive index: n20/D 1.44 (lit.)
bp: 167 °C (lit.)
density: 0.928 g/mL at 25 °C (lit.)
SMILES string: CN(C)CCCOC(=O)C=C
InChI: 1S/C8H15NO2/c1-4-8(10)11-7-5-6-9(2)3/h4H,1,5-7H2,2-3H3
InChI key: UFQHFMGRRVQFNA-UHFFFAOYSA-N
Quality Level:
__
Assay:
95%
form:
liquid
refractive index:
n20/D 1.44 (lit.)
bp:
167 °C (lit.)
density:
0.928 g/mL at 25 °C (lit.)
SMILES string:
CN(C)CCCOC(=O)C=C
InChI:
1S/C8H15NO2/c1-4-8(10)11-7-5-6-9(2)3/h4H,1,5-7H2,2-3H3
InChI key:
UFQHFMGRRVQFNA-UHFFFAOYSA-N
Quality Level: 100
Assay: ≥95%
form: liquid
refractive index: n20/D 1.428
bp: __
density: 0.777 g/mL at 20 °C (lit.)
SMILES string: C[Si]1(C)CCC1
InChI: 1S/C5H12Si/c1-6(2)4-3-5-6/h3-5H2,1-2H3
InChI key: YQQFFTNDQFUNHB-UHFFFAOYSA-N
Quality Level:
100
Assay:
≥95%
form:
liquid
refractive index:
n20/D 1.428
bp:
__
density:
0.777 g/mL at 20 °C (lit.)
SMILES string:
C[Si]1(C)CCC1
InChI:
1S/C5H12Si/c1-6(2)4-3-5-6/h3-5H2,1-2H3
InChI key:
YQQFFTNDQFUNHB-UHFFFAOYSA-N
Quality Level: 100
Assay: ≥99.0% (GC)
form: liquid
refractive index: __
bp: __
density: 1.408 g/mL at 20 °C (lit.)
SMILES string: C[Se]C
InChI: 1S/C2H6Se/c1-3-2/h1-2H3
InChI key: RVIXKDRPFPUUOO-UHFFFAOYSA-N
Quality Level:
100
Assay:
≥99.0% (GC)
form:
liquid
refractive index:
__
bp:
__
density:
1.408 g/mL at 20 °C (lit.)
SMILES string:
C[Se]C
InChI:
1S/C2H6Se/c1-3-2/h1-2H3
InChI key:
RVIXKDRPFPUUOO-UHFFFAOYSA-N