418080
Pentafluorophenyl diphenylphosphinate
Manufacturer: Sigma Aldrich
CAS Number: 138687-69-1
Synonym(S): FDPP, Diphenylphosphinic acid pentafluorophenyl ester
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 418080-1-G | In Stock | ₹ 3,052.65 |
| 5 G | 418080-5-G | In Stock | ₹ 10,435.30 |
418080 - 1 G
In Stock
Quantity
1
Base Price: ₹ 3,052.65
GST (18%): ₹ 549.477
Total Price: ₹ 3,602.127
form
solid
Quality Level
100
mp
47-50 °C (lit.)
SMILES string
Fc1c(F)c(F)c(OP(=O)(c2ccccc2)c3ccccc3)c(F)c1F
InChI
1S/C18H10F5O2P/c19-13-14(20)16(22)18(17(23)15(13)21)25-26(24,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChI key
OOWSDKUFKGVADH-UHFFFAOYSA-N
Related Products
Description
- General description: Pentafluorophenyl diphenylphosphinate (FDPP) is a reagent, used as a coupling agent in the amide bond forming reactions without racemization. It can also be employed in the synthesis of dipeptides with high yields and good optical purity. [1][2] FDPP can be prepared from diphenylphosphinic chloride and pentafluorophenol in the presence of imidazole.[2]
- Application: Catalyst involved in coupling and macrocyclizationReagent used in: Fmoc solid-phase synthesisSynthesis of phorboxazoles, furan-based cyclic homoligopeptides, and ziziphine N
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
form: solid
Quality Level: 100
mp: 47-50 °C (lit.)
SMILES string: Fc1c(F)c(F)c(OP(=O)(c2ccccc2)c3ccccc3)c(F)c1F
InChI: 1S/C18H10F5O2P/c19-13-14(20)16(22)18(17(23)15(13)21)25-26(24,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChI key: OOWSDKUFKGVADH-UHFFFAOYSA-N
form:
solid
Quality Level:
100
mp:
47-50 °C (lit.)
SMILES string:
Fc1c(F)c(F)c(OP(=O)(c2ccccc2)c3ccccc3)c(F)c1F
InChI:
1S/C18H10F5O2P/c19-13-14(20)16(22)18(17(23)15(13)21)25-26(24,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChI key:
OOWSDKUFKGVADH-UHFFFAOYSA-N
form: liquid
Quality Level: 200
mp: __
SMILES string: __
InChI: __
InChI key: __
form:
liquid
Quality Level:
200
mp:
__
SMILES string:
__
InChI:
__
InChI key:
__
form: liquid
Quality Level: 100
mp: −65 °C (lit.)
SMILES string: __
InChI: __
InChI key: __
form:
liquid
Quality Level:
100
mp:
−65 °C (lit.)
SMILES string:
__
InChI:
__
InChI key:
__
form: powder
Quality Level: 200
mp: >300 °C (lit.)
SMILES string: [Na]Sc1ccccc1
InChI: 1S/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
InChI key: RZWQDAUIUBVCDD-UHFFFAOYSA-M
form:
powder
Quality Level:
200
mp:
>300 °C (lit.)
SMILES string:
[Na]Sc1ccccc1
InChI:
1S/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
InChI key:
RZWQDAUIUBVCDD-UHFFFAOYSA-M