115754

2,2,6,6-Tetramethylpiperidine

≥99%

Manufacturer: Sigma Aldrich

CAS Number: 768-66-1

Synonym(S): 2,2,6,6-tetramethylpiperidide, 2,2,6,6-tetramethylpiperidine, Norpempidine, TEMP, TMPH

Select a Size

Pack Size SKU Availability Price
5 G 115754-5-G In Stock ₹ 3,850.00
10 G 115754-10-G In Stock ₹ 6,150.00
25 G 115754-25-G In Stock ₹ 11,890.00

115754 - 5 G

₹ 3,850.00

In Stock

Quantity

1

Base Price: ₹ 3,850.00

GST (18%): ₹ 693.00

Total Price: ₹ 4,543.00

Quality Level

200

Assay

≥99%

refractive index

n20/D 1.445 (lit.)

bp

152 °C (lit.)

density

0.837 g/mL at 25 °C (lit.)

SMILES string

CC1(C)CCCC(C)(C)N1

InChI

1S/C9H19N/c1-8(2)6-5-7-9(3,4)10-8/h10H,5-7H2,1-4H3

InChI key

RKMGAJGJIURJSJ-UHFFFAOYSA-N

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Description

  • General description: 2,2,6,6-Tetramethylpiperidineis a hindered secondary amine that is used to prepare metallo-amide bases and selective generation of silylketene acetals.
  • Application: 2,2,6,6-Tetramethylpiperidine can be used as a reactant to synthesize:Allylated tertiary amines via allylic amination of allylic chlorides.Hydroxylamines via oxidation in the presence of oxone as an oxidant.Sulfenamide compounds by reacting with heterocyclic thiols in the presence of iodine as an oxidant.N-methylated amines via N-methylation by reacting with CO2 and phenylsilane.Propargylamines via three-component Mannich coupling reaction with aldehydes and alkynes.

SAFETY INFORMATION

Pictograms

GHS02,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H226,H290,H302,H314,H335

Precautionary Statements

P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 2

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
200

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≥99%

refractive index:
n20/D 1.445 (lit.)

bp:
152 °C (lit.)

density:
0.837 g/mL at 25 °C (lit.)

SMILES string:
CC1(C)CCCC(C)(C)N1

InChI:
1S/C9H19N/c1-8(2)6-5-7-9(3,4)10-8/h10H,5-7H2,1-4H3

InChI key:
RKMGAJGJIURJSJ-UHFFFAOYSA-N

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Oc1ccccc1-c2ccccc2O

InChI:
1S/C12H10O2/c13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8,13-14H

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BrCC(=O)c1ccccc1

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LIGACIXOYTUXAW-UHFFFAOYSA-N