235032

Bis(trimethylsilyl) malonate

98%

Manufacturer: Sigma Aldrich

CAS Number: 18457-04-0

Synonym(S): Malonic acid bis(trimethylsilyl ester)

Select a Size

Pack Size SKU Availability Price
10 G 235032-10-G In Stock ₹ 11,052.33

235032 - 10 G

₹ 11,052.33

In Stock

Quantity

1

Base Price: ₹ 11,052.33

GST (18%): ₹ 1,989.419

Total Price: ₹ 13,041.749

Quality Level

200

Assay

98%

refractive index

n20/D 1.416 (lit.)

bp

63-66 °C/1 mmHg (lit.)

density

0.974 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)OC(=O)CC(=O)O[Si](C)(C)C

InChI

1S/C9H20O4Si2/c1-14(2,3)12-8(10)7-9(11)13-15(4,5)6/h7H2,1-6H3

InChI key

ATCKJLDGNXGLAO-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
CS-0073875
Bis(trimethylsilyl) malonate
ChemScene ₹ 8,727.12
AB71327
18457-04-0 | Bis(trimethylsilyl) malonate
A2B Chem ₹ 2,566.80 - ₹ 10,438.32

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Description

  • General description: Bis(trimethylsilyl) malonate is precursor for metal-organic chemical vapor deposition (MOCVD) of HfO2 and ZrO2 thin films[1]. It undergoes acylation reaction with acid chlorides and acyl carbonates in the presence of triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones[2].
  • Application: Bis(trimethylsilyl) malonate was used as cyclocondensation agent in cyclocondensation reactions[3]. It was also used in the preparation of β-keto acids and methyl ketones[4].

SAFETY INFORMATION

Pictograms

GHS02

Signal Word

Warning

Hazard Statements

H226

Hazard Classifications

Flam. Liq. 3

WGK

WGK 3

Flash Point(F)

75.2 °F

Flash Point(C)

24 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

235032

98%...


Quality Level:
200

Assay:
98%

refractive index:
n20/D 1.416 (lit.)

bp:
63-66 °C/1 mmHg (lit.)

density:
0.974 g/mL at 25 °C (lit.)

SMILES string:
C[Si](C)(C)OC(=O)CC(=O)O[Si](C)(C)C

InChI:
1S/C9H20O4Si2/c1-14(2,3)12-8(10)7-9(11)13-15(4,5)6/h7H2,1-6H3

InChI key:
ATCKJLDGNXGLAO-UHFFFAOYSA-N

Img

Sigma Aldrich

235040

98%...


Quality Level:
100

Assay:
98%

refractive index:
n20/D 1.502 (lit.)

bp:
88-89 °C/11 mmHg (lit.)

density:
0.938 g/mL at 25 °C (lit.)

SMILES string:
C[Si](C)(C)OC(=C)c1ccccc1

InChI:
1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3

InChI key:
__

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Sigma Aldrich

235067

99%...


Quality Level:
200

Assay:
99%

refractive index:
n20/D 1.43 (lit.)

bp:
142-144 °C (lit.)

density:
0.898 g/mL at 25 °C (lit.)

SMILES string:
CC[Si](Cl)(CC)CC

InChI:
1S/C6H15ClSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3

InChI key:
DCFKHNIGBAHNSS-UHFFFAOYSA-N

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Sigma Aldrich

235083

95%...


Quality Level:
100

Assay:
95%

refractive index:
__

bp:
__

density:
__

SMILES string:
C[Si](C)(C)N([Na])[Si](C)(C)C

InChI:
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key:
WRIKHQLVHPKCJU-UHFFFAOYSA-N