248835
p-Toluenesulfonyl cyanide
technical grade, 95%
Manufacturer: Sigma Aldrich
CAS Number: 19158-51-1
Synonym(S): p-Tolylsulfonyl cyanide, Tosyl cyanide
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 248835-1-G | In Stock | ₹ 8,811.55 |
| 5 G | 248835-5-G | In Stock | ₹ 22,299.50 |
248835 - 1 G
In Stock
Quantity
1
Base Price: ₹ 8,811.55
GST (18%): ₹ 1,586.079
Total Price: ₹ 10,397.629
grade
technical grade
Quality Level
100
Assay
95%
form
solid
bp
105-106 °C/1 mmHg (lit.)
mp
47-50 °C (lit.)
storage temp.
2-8°C
SMILES string
Cc1ccc(cc1)S(=O)(=O)C#N
InChI
1S/C8H7NO2S/c1-7-2-4-8(5-3-7)12(10,11)6-9/h2-5H,1H3
InChI key
JONIMGVUGJVFQD-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules AstaTech / 4-METHYLBENZENESULFONYL CYANIDE / 1g / 412394921 / H10452 / 97.000 / 19158-51-1 / MFCD00009977 / 181.210 / C8H7NO2S | eMolecules | ₹ 3,379.62 | |
| | Sigma Aldrich Fine Chemicals Biosciences p-Toluenesulfonyl cyanide technical grade, 95% | 19158-51-1 | MFCD00009977 | 1G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 9,349.14 | |
 | Chemscene AbaChemscene,4-Methylbenzenesulfonyl cyanide,19158-51-1,Formula:C8H7NO2S,M. Wt. 181.21,>98.0% | Chemscene | ₹ 3,022.83 | |
| | eMolecules Tosyl cyanide | 19158-51-1 | MFCD00009977 | 5g | eMolecules | ₹ 17,002.48 | |
 | 19158-51-1 | Tosyl cyanide | A2B Chem | ₹ 1,454.52 - ₹ 14,545.20 |
Related Products
Description
- General description: p-Toluenesulfonyl cyanide is an electron-deficient nitrile. It undergoes hetero-Diels-Alder reaction with silyl enol ether of cyclohexenone to yield hydrolytically sensitive [4+2] adduct.[1] It also undergoes facile [2+3] cycloaddition reaction with azides to form 5-sulfonyl tetrazoles.[2] p-Toluenesulfonyl cyanide also reacts with alcohols in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) or 1,4-diazabicyclo[2.2.2]octane (DABCO) to yield sulfinates.[3]
- Application: p-Toluenesulfonyl cyanide can be used in:The preparation of polyfunctional nitriles.[4]Free-radical cyanation of B-alkylcatecholboranes.[5]The synthesis of 4-hyroxypyridines by hetero-Diels-Alder reaction with 1,3-bis-silyl enol ethers.[6]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
230.0 °F
Flash Point(C)
110 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
grade: technical grade
Quality Level: 100
Assay: 95%
form: solid
bp: 105-106 °C/1 mmHg (lit.)
mp: 47-50 °C (lit.)
storage temp.: 2-8°C
SMILES string: Cc1ccc(cc1)S(=O)(=O)C#N
InChI: 1S/C8H7NO2S/c1-7-2-4-8(5-3-7)12(10,11)6-9/h2-5H,1H3
InChI key: JONIMGVUGJVFQD-UHFFFAOYSA-N
grade:
technical grade
Quality Level:
100
Assay:
95%
form:
solid
bp:
105-106 °C/1 mmHg (lit.)
mp:
47-50 °C (lit.)
storage temp.:
2-8°C
SMILES string:
Cc1ccc(cc1)S(=O)(=O)C#N
InChI:
1S/C8H7NO2S/c1-7-2-4-8(5-3-7)12(10,11)6-9/h2-5H,1H3
InChI key:
JONIMGVUGJVFQD-UHFFFAOYSA-N
grade: __
Quality Level: __
Assay: __
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bp: __
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SMILES string:
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InChI:
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grade: __
Quality Level: 100
Assay: ≥98%
form: solid
bp: __
mp: __
storage temp.: __
SMILES string: __
InChI: 1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)
InChI key: JEHUZVBIUCAMRZ-UHFFFAOYSA-N
grade:
__
Quality Level:
100
Assay:
≥98%
form:
solid
bp:
__
mp:
__
storage temp.:
__
SMILES string:
__
InChI:
1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)
InChI key:
JEHUZVBIUCAMRZ-UHFFFAOYSA-N
grade: __
Quality Level: 100
Assay: __
form: __
bp: __
mp: __
storage temp.: __
SMILES string: CCCCCCCCCCCCOc1c(C)c([Hg]Cl)c([Hg]Cl)c(C)c1OCCCCCCCCCCCC
InChI: 1S/C32H56O2.2ClH.2Hg/c1-5-7-9-11-13-15-17-19-21-23-27-33-31-29(3)25-26-30(4)32(31)34-28-24-22-20-18-16-14-12-10-8-6-2;;;;/h5-24,27-28H2,1-4H3;2*1H;;/q;;;2*+1/p-2
InChI key: SSQLFLVGBOQWGG-UHFFFAOYSA-L
grade:
__
Quality Level:
100
Assay:
__
form:
__
bp:
__
mp:
__
storage temp.:
__
SMILES string:
CCCCCCCCCCCCOc1c(C)c([Hg]Cl)c([Hg]Cl)c(C)c1OCCCCCCCCCCCC
InChI:
1S/C32H56O2.2ClH.2Hg/c1-5-7-9-11-13-15-17-19-21-23-27-33-31-29(3)25-26-30(4)32(31)34-28-24-22-20-18-16-14-12-10-8-6-2;;;;/h5-24,27-28H2,1-4H3;2*1H;;/q;;;2*+1/p-2
InChI key:
SSQLFLVGBOQWGG-UHFFFAOYSA-L