269697
Ethyl 4,4,4-trifluorocrotonate
98%
Manufacturer: Sigma Aldrich
CAS Number: 406-10-0
Synonym(S): Ethyl 4,4,4-trifluoro-2-butenoate
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| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 G | 269697-5-G | In Stock | ₹ 3,355.75 |
269697 - 5 G
In Stock
Quantity
1
Base Price: ₹ 3,355.75
GST (18%): ₹ 604.035
Total Price: ₹ 3,959.785
Quality Level
100
Assay
98%
form
liquid
refractive index
n20/D 1.3601 (lit.)
bp
114-115 °C (lit.)
density
1.125 g/mL at 25 °C (lit.)
SMILES string
CCOC(=O)\C=C\C(F)(F)F
InChI
1S/C6H7F3O2/c1-2-11-5(10)3-4-6(7,8)9/h3-4H,2H2,1H3/b4-3+
InChI key
ZKRJCMKLCDWROR-ONEGZZNKSA-N
Related Products
Description
- General description: The Michael reaction between ethyl 4,4,4-trifluorocrotonate and a Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone was studied[1].
- Application: Ethyl 4,4,4-trifluorocrotonate was used in the synthesis of (2S,3S)-3-methyl- and (2S,3S)-3-trifluoromethylpyroglutamic acid. It undergoes diastereoselective Michael addition reaction with ethyl crotonate[2].
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
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Quality Level: 100
Assay: 98%
form: liquid
refractive index: n20/D 1.3601 (lit.)
bp: 114-115 °C (lit.)
density: 1.125 g/mL at 25 °C (lit.)
SMILES string: CCOC(=O)\C=C\C(F)(F)F
InChI: 1S/C6H7F3O2/c1-2-11-5(10)3-4-6(7,8)9/h3-4H,2H2,1H3/b4-3+
InChI key: ZKRJCMKLCDWROR-ONEGZZNKSA-N
Quality Level:
100
Assay:
98%
form:
liquid
refractive index:
n20/D 1.3601 (lit.)
bp:
114-115 °C (lit.)
density:
1.125 g/mL at 25 °C (lit.)
SMILES string:
CCOC(=O)\C=C\C(F)(F)F
InChI:
1S/C6H7F3O2/c1-2-11-5(10)3-4-6(7,8)9/h3-4H,2H2,1H3/b4-3+
InChI key:
ZKRJCMKLCDWROR-ONEGZZNKSA-N
Quality Level: 200
Assay: ≥99.0% (AT)
form: powder or crystals
refractive index: __
bp: __
density: __
SMILES string: __
InChI: __
InChI key: __
Quality Level:
200
Assay:
≥99.0% (AT)
form:
powder or crystals
refractive index:
__
bp:
__
density:
__
SMILES string:
__
InChI:
__
InChI key:
__
Quality Level: 200
Assay: ≥99% (CP)
form: liquid
refractive index: n20/D 1.403 (lit.)
bp: 65-66 °C (lit.)
density: 0.985 g/mL at 25 °C (lit.)
SMILES string: __
InChI: __
InChI key: __
Quality Level:
200
Assay:
≥99% (CP)
form:
liquid
refractive index:
n20/D 1.403 (lit.)
bp:
65-66 °C (lit.)
density:
0.985 g/mL at 25 °C (lit.)
SMILES string:
__
InChI:
__
InChI key:
__
Quality Level: 200
Assay: ≥98.0% (NMR)
form: __
refractive index: __
bp: __
density: __
SMILES string: [Na+].[2H]C([2H])(C([O-])=O)C([2H])([2H])[Si](C)(C)C
InChI: 1S/C6H14O2Si.Na/c1-9(2,3)5-4-6(7)8;/h4-5H2,1-3H3,(H,7,8);/q;+1/p-1/i4D2,5D2;
InChI key: OIIWPAYIXDCDNL-HGFPCDIYSA-M
Quality Level:
200
Assay:
≥98.0% (NMR)
form:
__
refractive index:
__
bp:
__
density:
__
SMILES string:
[Na+].[2H]C([2H])(C([O-])=O)C([2H])([2H])[Si](C)(C)C
InChI:
1S/C6H14O2Si.Na/c1-9(2,3)5-4-6(7)8;/h4-5H2,1-3H3,(H,7,8);/q;+1/p-1/i4D2,5D2;
InChI key:
OIIWPAYIXDCDNL-HGFPCDIYSA-M