274585

Methyl trimethylsilyl dimethylketene acetal

95%

Manufacturer: Sigma Aldrich

CAS Number: 31469-15-5

Synonym(S): 1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, (1-Methoxy-2-methyl-1-propenyloxy)trimethylsilane, MTDA

Select a Size

Pack Size SKU Availability Price
5 G 274585-5-G In Stock ₹ 4,620.00
25 G 274585-25-G In Stock ₹ 19,680.00
100 G 274585-100-G In Stock ₹ 55,940.00

274585 - 5 G

₹ 4,620.00

In Stock

Quantity

1

Base Price: ₹ 4,620.00

GST (18%): ₹ 831.60

Total Price: ₹ 5,451.60

Quality Level

100

Assay

95%

form

liquid

refractive index

n20/D 1.415 (lit.)

bp

35 °C/15 mmHg (lit.)

density

0.858 g/mL at 25 °C (lit.)

SMILES string

CO\C(O[Si](C)(C)C)=C(/C)C

InChI

1S/C8H18O2Si/c1-7(2)8(9-3)10-11(4,5)6/h1-6H3

InChI key

JNOGVQJEBGEKMG-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
AB45943
31469-15-5 | Dimethylketene methyl trimethylsilyl acetal
A2B Chem ₹ 1,112.28 - ₹ 4,534.68

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Description

  • Application: Methyl trimethylsilyl dimethylketene acetal was used:in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachlorideas a catalyst[1][2] or initiator[3] in the group-transfer polymerizationas a versatile reagent in conjugate addition[4] and aldol reactions[5][6].

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319,H335

Precautionary Statements

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Sigma Aldrich

274585

95%...


Quality Level:
100

Assay:
95%

form:
liquid

refractive index:
n20/D 1.415 (lit.)

bp:
35 °C/15 mmHg (lit.)

density:
0.858 g/mL at 25 °C (lit.)

SMILES string:
CO\C(O[Si](C)(C)C)=C(/C)C

InChI:
1S/C8H18O2Si/c1-7(2)8(9-3)10-11(4,5)6/h1-6H3

InChI key:
JNOGVQJEBGEKMG-UHFFFAOYSA-N

Img

Sigma Aldrich

274593

98%...


Quality Level:
__

Assay:
98%

form:
solid

refractive index:
__

bp:
__

density:
__

SMILES string:
O.[Na+].[Na+].[O-]C(=O)CN(CCN1CCN2CC(=O)O[Fe](OC(=O)C1)OC(=O)C2)CC([O-])=O

InChI:
1S/C14H23N3O10.Fe.2Na.H2O/c18-10(19)5-15(1-3-16(6-11(20)21)7-12(22)23)2-4-17(8-13(24)25)9-14(26)27;;;;/h1-9H2,(H,18,19)(H,20,21)(H,22,23)(H,24,25)(H,26,27);;;;1H2/q;+3;2*+1;/p-5

InChI key:
QPJPBTBEMHBPHZ-UHFFFAOYSA-I

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274623

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Assay:
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bp:
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SMILES string:
CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc12

InChI:
1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3

InChI key:
NKLCNNUWBJBICK-UHFFFAOYSA-N

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Sigma Aldrich

274658

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Quality Level:
100

Assay:
95%

form:
liquid

refractive index:
n20/D 1.476 (lit.)

bp:
100 °C/30 mmHg (lit.)

density:
0.917 g/mL at 25 °C (lit.)

SMILES string:
CC1C(C)C(=O)C(C)=C1C

InChI:
1S/C9H14O/c1-5-6(2)8(4)9(10)7(5)3/h5,7H,1-4H3

InChI key:
ARUAYSANQMCCEN-UHFFFAOYSA-N