360031

(Triisopropylsilyl)acetylene

97%

Manufacturer: Sigma Aldrich

CAS Number: 89343-06-6

Synonym(S): Ethynyltriisopropylsilane

Select a Size

Pack Size SKU Availability Price
5 G 360031-5-G In Stock ₹ 10,705.93
25 G 360031-25-G In Stock ₹ 28,686.25

360031 - 5 G

₹ 10,705.93

In Stock

Quantity

1

Base Price: ₹ 10,705.93

GST (18%): ₹ 1,927.067

Total Price: ₹ 12,632.997

Quality Level

100

Assay

97%

form

liquid

refractive index

n20/D 1.4527 (lit.)

bp

50-52 °C/0.6 mmHg (lit.)

density

0.813 g/mL at 25 °C (lit.)

SMILES string

CC(C)[Si](C#C)(C(C)C)C(C)C

InChI

1S/C11H22Si/c1-8-12(9(2)3,10(4)5)11(6)7/h1,9-11H,2-7H3

InChI key

KZGWPHUWNWRTEP-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-681-473
Matrix Scientific Triisopropylsilylacetylene, 89343-06-6, MFCD00075452, 5g
Matrix Scientific ₹ 3,358.23
AB46153
89343-06-6 | (Triisopropylsilyl)acetylene
A2B Chem ₹ 598.92 - ₹ 30,887.16

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Description

  • General description: Asymmetric addition of (triisopropylsilyl)acetylene to α,β,γ,δ-unsaturated carbonyl compounds in the presence of a cobalt/Duphos catalyst is reported.[1] A Sonogashira coupling reaction between 1-bromo-3-iodo-5-tertbutylbenzene and (triisopropylsilyl)acetylene is reported.[2]
  • Application: (Triisopropylsilyl)acetylene may be used as reagent for the rhodium-catalyzed asymmetric alkynylation of various α,β-unsaturated ketones.[3] It may be used as reagent in the enantioselective synthesis of β-alkynylated nitroalkanes.[4]

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319,H335

Precautionary Statements

P210 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

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form:
liquid

refractive index:
n20/D 1.4527 (lit.)

bp:
50-52 °C/0.6 mmHg (lit.)

density:
0.813 g/mL at 25 °C (lit.)

SMILES string:
CC(C)[Si](C#C)(C(C)C)C(C)C

InChI:
1S/C11H22Si/c1-8-12(9(2)3,10(4)5)11(6)7/h1,9-11H,2-7H3

InChI key:
KZGWPHUWNWRTEP-UHFFFAOYSA-N

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C#C[Si](c1ccccc1)(c2ccccc2)c3ccccc3

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1S/C20H16Si/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20/h1,3-17H

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WADKYPSVXRWORK-UHFFFAOYSA-N

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