377775
3-Bromo-1-(trimethylsilyl)-1-propyne
98%
Manufacturer: Sigma Aldrich
CAS Number: 38002-45-8
Synonym(S): 3-(Trimethylsilyl)propargyl bromide, 3-Bromo-1-(trimethylsilyl)-1-propyne
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 377775-1-G | In Stock | ₹ 3,756.28 |
| 10 G | 377775-10-G | In Stock | ₹ 25,492.88 |
377775 - 1 G
In Stock
Quantity
1
Base Price: ₹ 3,756.28
GST (18%): ₹ 676.13
Total Price: ₹ 4,432.41
Quality Level
100
Assay
98%
form
liquid
refractive index
n20/D 1.483 (lit.)
bp
44-45 °C/2 mmHg (lit.)
density
1.17 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C[Si](C)(C)C#CCBr
InChI
1S/C6H11BrSi/c1-8(2,3)6-4-5-7/h5H2,1-3H3
InChI key
GAPRPFRDVCCCHR-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences 3-Bromo-1-(trimethylsilyl)-1-propyne 98% | 38002-45-8 | MFCD00134460 | 10G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 32,072.17 | |
| | Sigma Aldrich Fine Chemicals Biosciences 3-Bromo-1-(trimethylsilyl)-1-propyne 98% | 38002-45-8 | MFCD00134460 | 1G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 6,031.98 | |
 | (3-Bromoprop-1-yn-1-yl)trimethylsilane | ChemScene | ₹ 427.80 - ₹ 41,582.16 | |
 | 38002-45-8 | 3-Bromo-1-(trimethylsilyl)-1-propyne | A2B Chem | ₹ 342.24 - ₹ 7,957.08 |
Related Products
Description
- General description: 3-Bromo-1-(trimethylsilyl)-1-propyne is reported as a propargylating agent.[1] Selective reaction of 3-bromo-1-(trimethylsilyl)-1-propyne with α-keto ester using indium metal has been studied.[2]
- Application: 3-Bromo-1-(trimethylsilyl)-1-propyne may be used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives.[3] It may be used as reagent for the alkylation of dianion of β-keto esters at γ-carbon.[4] It may be employed in the preparation of terminal conjugated enynes[5] and allenic alcohols.[6]
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
145.4 °F
Flash Point(C)
63 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 98%
form: liquid
refractive index: n20/D 1.483 (lit.)
bp: 44-45 °C/2 mmHg (lit.)
density: 1.17 g/mL at 25 °C (lit.)
storage temp.: 2-8°C
SMILES string: C[Si](C)(C)C#CCBr
InChI: 1S/C6H11BrSi/c1-8(2,3)6-4-5-7/h5H2,1-3H3
InChI key: GAPRPFRDVCCCHR-UHFFFAOYSA-N
Quality Level:
100
Assay:
98%
form:
liquid
refractive index:
n20/D 1.483 (lit.)
bp:
44-45 °C/2 mmHg (lit.)
density:
1.17 g/mL at 25 °C (lit.)
storage temp.:
2-8°C
SMILES string:
C[Si](C)(C)C#CCBr
InChI:
1S/C6H11BrSi/c1-8(2,3)6-4-5-7/h5H2,1-3H3
InChI key:
GAPRPFRDVCCCHR-UHFFFAOYSA-N
Quality Level: 200
Assay: 96%
form: __
refractive index: __
bp: __
density: __
storage temp.: __
SMILES string: CC1(C)CC2(CC(C)(C)c3cc(O)c(O)cc23)c4cc(O)c(O)cc14
InChI: 1S/C21H24O4/c1-19(2)9-21(13-7-17(24)15(22)5-11(13)19)10-20(3,4)12-6-16(23)18(25)8-14(12)21/h5-8,22-25H,9-10H2,1-4H3
InChI key: POFMQEVZKZVAPQ-UHFFFAOYSA-N
Quality Level:
200
Assay:
96%
form:
__
refractive index:
__
bp:
__
density:
__
storage temp.:
__
SMILES string:
CC1(C)CC2(CC(C)(C)c3cc(O)c(O)cc23)c4cc(O)c(O)cc14
InChI:
1S/C21H24O4/c1-19(2)9-21(13-7-17(24)15(22)5-11(13)19)10-20(3,4)12-6-16(23)18(25)8-14(12)21/h5-8,22-25H,9-10H2,1-4H3
InChI key:
POFMQEVZKZVAPQ-UHFFFAOYSA-N
Quality Level: 200
Assay: 98%
form: powder, crystals or chunks
refractive index: __
bp: __
density: __
storage temp.: 2-8°C
SMILES string: F[P-](F)(F)(F)(F)F.C1CCN(C1)[P+](On2nnc3ccccc23)(N4CCCC4)N5CCCC5
InChI: 1S/C18H28N6OP.F6P/c1-2-10-18-17(9-1)19-20-24(18)25-26(21-11-3-4-12-21,22-13-5-6-14-22)23-15-7-8-16-23;1-7(2,3,4,5)6/h1-2,9-10H,3-8,11-16H2;/q+1;-1
InChI key: __
Quality Level:
200
Assay:
98%
form:
powder, crystals or chunks
refractive index:
__
bp:
__
density:
__
storage temp.:
2-8°C
SMILES string:
F[P-](F)(F)(F)(F)F.C1CCN(C1)[P+](On2nnc3ccccc23)(N4CCCC4)N5CCCC5
InChI:
1S/C18H28N6OP.F6P/c1-2-10-18-17(9-1)19-20-24(18)25-26(21-11-3-4-12-21,22-13-5-6-14-22)23-15-7-8-16-23;1-7(2,3,4,5)6/h1-2,9-10H,3-8,11-16H2;/q+1;-1
InChI key:
__
Quality Level: 100
Assay: 99%
form: __
refractive index: __
bp: 180 °C/3 mmHg (lit.)
density: __
storage temp.: __
SMILES string: [O-][N+](=O)c1cccc(CC#N)c1
InChI: 1S/C8H6N2O2/c9-5-4-7-2-1-3-8(6-7)10(11)12/h1-3,6H,4H2
InChI key: WAVKEPUFQMUGBP-UHFFFAOYSA-N
Quality Level:
100
Assay:
99%
form:
__
refractive index:
__
bp:
180 °C/3 mmHg (lit.)
density:
__
storage temp.:
__
SMILES string:
[O-][N+](=O)c1cccc(CC#N)c1
InChI:
1S/C8H6N2O2/c9-5-4-7-2-1-3-8(6-7)10(11)12/h1-3,6H,4H2
InChI key:
WAVKEPUFQMUGBP-UHFFFAOYSA-N