378895
Piperonyloyl chloride
99%
Manufacturer: Sigma Aldrich
CAS Number: 25054-53-9
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 378895-1-G | In Stock | ₹ 5,434.15 |
| 10 G | 378895-10-G | In Stock | ₹ 26,607.85 |
378895 - 1 G
In Stock
Quantity
1
Base Price: ₹ 5,434.15
GST (18%): ₹ 978.147
Total Price: ₹ 6,412.297
Quality Level
100
Assay
99%
bp
155 °C/25 mmHg (lit.)
mp
78-79 °C (lit.)
SMILES string
ClC(=O)c1ccc2OCOc2c1
InChI
1S/C8H5ClO3/c9-8(10)5-1-2-6-7(3-5)12-4-11-6/h1-3H,4H2
InChI key
ZRSGZIMDIHBXIN-UHFFFAOYSA-N
Description
- General description: Piperonyloyl chloride is an acyl halide. It participates in the preparation of starting reagent (N-acyl indole), required for the synthesis of pyrrolophenanthridone alkaloids.[1] Kinetic study of the solvolysis of piperonyloyl chloride in various pure and binary solvent mixtures has been proposed. Solvolysis reaction has been reported to proceed via electron-rich acyl transfer mechanism.[2]
- Application: Piperonyloyl chloride is suitable for use in a kinetic study to evaluate the solvolysis rate constants of piperonyloyl chloride in 27 different solvents.[2] It may be used in the synthesis of the following compounds:2-phenylbenzimidazoles[3](Z)-3-hydroxy-1-(5-methoxy-2,2-dimethyl-2H-chromen-6-yl)-3-phenylprop-2-en-1-one[4]pongapinone A[4]2-((1-(2-(N-(4-chlorophenyl)benzo[d][1,3]dioxole-5-carboxamido)ethyl)piperidin-4-yl)oxy)acetic acid phosphoric acid salt, inhibitor of platelet aggregation[5]justicidin B, the piscicidal components of Justicia Hayatai var. decumbens[6]piperazine derivatives[7]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Quality Level: 100
Assay: 99%
bp: 155 °C/25 mmHg (lit.)
mp: 78-79 °C (lit.)
SMILES string: ClC(=O)c1ccc2OCOc2c1
InChI: 1S/C8H5ClO3/c9-8(10)5-1-2-6-7(3-5)12-4-11-6/h1-3H,4H2
InChI key: ZRSGZIMDIHBXIN-UHFFFAOYSA-N
Quality Level:
100
Assay:
99%
bp:
155 °C/25 mmHg (lit.)
mp:
78-79 °C (lit.)
SMILES string:
ClC(=O)c1ccc2OCOc2c1
InChI:
1S/C8H5ClO3/c9-8(10)5-1-2-6-7(3-5)12-4-11-6/h1-3H,4H2
InChI key:
ZRSGZIMDIHBXIN-UHFFFAOYSA-N
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SMILES string: C1CCC(CC1)N=C=NC2CCCCC2
InChI: 1S/C13H22N2/c1-3-7-12(8-4-1)14-11-15-13-9-5-2-6-10-13/h12-13H,1-10H2
InChI key: QOSSAOTZNIDXMA-UHFFFAOYSA-N
Quality Level:
200
Assay:
__
bp:
__
mp:
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SMILES string:
C1CCC(CC1)N=C=NC2CCCCC2
InChI:
1S/C13H22N2/c1-3-7-12(8-4-1)14-11-15-13-9-5-2-6-10-13/h12-13H,1-10H2
InChI key:
QOSSAOTZNIDXMA-UHFFFAOYSA-N