391638

Dimethylphosphoramidous dichloride

97%

Manufacturer: Sigma Aldrich

CAS Number: 683-85-2

Synonym(S): (Dichlorophosphanyl)dimethylamine, (Dimethylamino)dichlorophosphine, Dichloro(dimethylamido)phosphorus, Dichloro(dimethylamino)phosphine, Dichloro-N,N-dimethylaminophosphine, N,N-Dimethylphosphoramidous dichloride

Select a Size

Pack Size SKU Availability Price
25 ML 391638-25-ML In Stock ₹ 23,270.00

391638 - 25 ML

₹ 23,270.00

In Stock

Quantity

1

Base Price: ₹ 23,270.00

GST (18%): ₹ 4,188.60

Total Price: ₹ 27,458.60

Quality Level

100

Assay

97%

form

liquid

refractive index

n20/D 1.505 (lit.)

bp

150 °C (lit.)

density

1.271 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CN(C)P(Cl)Cl

InChI

1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3

InChI key

XPWWDZRSNFSLRQ-UHFFFAOYSA-N

Description

  • General description: Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative.[1] It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry.[2] Its synthesis has been reported.[3] Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms.[1] Its vibrational spectra has been studied.[4] Its reaction with SO2 has been investigated.[5] It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.[6]
  • Application: Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:N,N-dimethylamidotetrachlorophosphorane[7]O-propylchloroformimino-N,N-dimethylamidochlorophosphate[7]1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines[8]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H225,H314

Precautionary Statements

P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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SMILES string:
CN(C)P(Cl)Cl

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1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3

InChI key:
XPWWDZRSNFSLRQ-UHFFFAOYSA-N

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JWBWFTANBHYHBC-UHFFFAOYSA-N

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CJXQAYQWVNXIQE-UHFFFAOYSA-N

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1S/C2H7N/c1-3-2/h3H,1-2H3

InChI key:
ROSDSFDQCJNGOL-UHFFFAOYSA-N