40288
6,6-Dimethylfulvene
≥95%
Manufacturer: Sigma Aldrich
CAS Number: 2175-91-9
Synonym(S): 5-(1-Methylethylidene)-1,3-cyclopentadiene, 5-Isopropylidene-1,3-cyclopentadiene
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 ML | 40288-5-ML | In Stock | ₹ 11,518.28 |
40288 - 5 ML
In Stock
Quantity
1
Base Price: ₹ 11,518.28
GST (18%): ₹ 2,073.29
Total Price: ₹ 13,591.57
Quality Level
100
Assay
≥95%
form
liquid
refractive index
n20/D 1.548 (lit.)n20/D 1.548
bp
76-77 °C/50 mmHg (lit.)
density
0.881 g/mL at 25 °C (lit.)
storage temp.
−20°C
SMILES string
C\C(C)=C1/C=CC=C1
InChI
1S/C8H10/c1-7(2)8-5-3-4-6-8/h3-6H,1-2H3
InChI key
WXACXMWYHXOSIX-UHFFFAOYSA-N
Related Products
Description
- General description: 6,6-Dimethylfulvene [5-(1-methylethylidene)-1,3-cyclopentadiene] is a nonaromatic carbocyclic analog of isopropylbenzene.[1] 6,6-Dimethylfulvene reacts with 2,2-bis(trifluoromethyl)-1,1-dicyanoethylene (BTF; 1) to afford the expected Diels-Alder cycloadduct, 7-(1-methylethylidene)-3,3-bis(trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2,2-dicarbonitrile.[2] Metal-free hydrogenation of 6,6-dimethylfulvene via frustrated Lewis pair (FLP) mediated triple domino reaction has been reported.[3]The biotransformation of 6,6-dimethylfulvene by Pseudomonas putida RE213 has been studied.Cycloaddition of 6,6-dimethylfulvene with benzynes has been reported.[4]
- Application: 6,6-Dimethylfulvene may be employed in the following studies:One-pot synthesis of ansa-metallocenes.[6] Synthesis of endo and exo-adducts with maleic anhydride.[7]Synthesis of fulvenols or the corresponding trimethylsilyl ethers.[8]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 3
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Quality Level: 100
Assay: ≥95%
form: liquid
refractive index: n20/D 1.548 (lit.)n20/D 1.548
bp: 76-77 °C/50 mmHg (lit.)
density: 0.881 g/mL at 25 °C (lit.)
storage temp.: −20°C
SMILES string: C\C(C)=C1/C=CC=C1
InChI: 1S/C8H10/c1-7(2)8-5-3-4-6-8/h3-6H,1-2H3
InChI key: WXACXMWYHXOSIX-UHFFFAOYSA-N
Quality Level:
100
Assay:
≥95%
form:
liquid
refractive index:
n20/D 1.548 (lit.)n20/D 1.548
bp:
76-77 °C/50 mmHg (lit.)
density:
0.881 g/mL at 25 °C (lit.)
storage temp.:
−20°C
SMILES string:
C\C(C)=C1/C=CC=C1
InChI:
1S/C8H10/c1-7(2)8-5-3-4-6-8/h3-6H,1-2H3
InChI key:
WXACXMWYHXOSIX-UHFFFAOYSA-N
Quality Level: 200
Assay: ≥98.5%
form: solid
refractive index: __
bp: __
density: __
storage temp.: __
SMILES string: __
InChI: __
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Quality Level:
200
Assay:
≥98.5%
form:
solid
refractive index:
__
bp:
__
density:
__
storage temp.:
__
SMILES string:
__
InChI:
__
InChI key:
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Quality Level: 200
Assay: ≥99.5%
form: liquid
refractive index: __
bp: __
density: __
storage temp.: __
SMILES string: __
InChI: __
InChI key: __
Quality Level:
200
Assay:
≥99.5%
form:
liquid
refractive index:
__
bp:
__
density:
__
storage temp.:
__
SMILES string:
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InChI:
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Quality Level: 200
Assay: ≥99.5%
form: powder or crystals
refractive index: __
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SMILES string: OC(C1=C(C(O)=O)C=CC=C1)=O
InChI: __
InChI key: __
Quality Level:
200
Assay:
≥99.5%
form:
powder or crystals
refractive index:
__
bp:
__
density:
__
storage temp.:
__
SMILES string:
OC(C1=C(C(O)=O)C=CC=C1)=O
InChI:
__
InChI key:
__