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449458

(tert-Butyldimethylsilyloxy)acetaldehyde

Name: (tert-Butyldimethylsilyloxy)acetaldehyde | Sigma Aldrich | Chemikart
Brand: Chemikart

90%

Manufacturer: Sigma Aldrich

CAS Number: 102191-92-4

Synonym(S): (tert-Butyldimethylsiloxy)acetaldehyde, 2-(tert-Butyldimethylsilyloxy)acetaldehyde, 2-[(tert-Butyl)dimethylsiloxy]acetaldehyde, 2-[(tert-Butyldimethylsilanyl)oxy]acetaldehyde, 2-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]acetaldehyde, Dimethyl-tert-butylsilyloxyacetaldehyde

Select a Size

Pack Size	SKU	Availability	Price
1 G	449458-1-G	In Stock	₹ 10,020.00
5 G	449458-5-G	In Stock	₹ 29,290.00

449458 - 1 G

₹ 10,020.00

In Stock

Quantity

Base Price: ₹ 10,020.00

GST (18%): ₹ 1,803.60

Total Price: ₹ 11,823.60

Assay

90%

refractive index

n20/D 1.432 (lit.)

bp

165-167 °C (lit.)

density

0.915 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(C)(C)[Si](C)(C)OCC=O

InChI

1S/C8H18O2Si/c1-8(2,3)11(4,5)10-7-6-9/h6H,7H2,1-5H3

InChI key

MEBFFOKESLAUSJ-UHFFFAOYSA-N

Other Options

Product Name	Manufacturer	Price Range
Sigma Aldrich Fine Chemicals Biosciences (tert-Butyldimethylsilyloxy)acetaldehyde 90% \| Purity: 90% \| Mol Wt: 174.31 \| 102191-92-4 \| MFCD01321229 \| 1G	Sigma Aldrich Fine Chemicals Biosciences	₹ 14,359.53
Sigma Aldrich Fine Chemicals Biosciences (tert-Butyldimethylsilyloxy)acetaldehyde 90% \| Purity: 90% \| Mol Wt: 174.31 \| 102191-92-4 \| MFCD01321229 \| 5G	Sigma Aldrich Fine Chemicals Biosciences	₹ 39,304.55
Acetaldehyde, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-	Aaron Chemicals LLC	₹ 342.24 - ₹ 1,31,847.96
102191-92-4 \| (tert-Butyldimethylsilyloxy)acetaldehyde	A2B Chem	₹ 427.80 - ₹ 12,235.08

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Description

Application: (tert-Butyldimethylsilyloxy)acetaldehyde is a versatile reagent commonly used in synthetic glycobiology.[1][2] It can act both as an aldol donor and an aldol acceptor in the stereocontrolled production of erythrose.[2] It is used as an important reagent in the total synthesis of (+)-ambruticin,[3] (−)-laulimalide,[4] (−)-salinosporamide A,[5] and (+)-leucascandrolide A.[6]

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319,H335

Precautionary Statements

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Sigma Aldrich

449458

90%...

Assay:

90%

refractive index:

n20/D 1.432 (lit.)

bp:

165-167 °C (lit.)

density:

0.915 g/mL at 25 °C (lit.)

storage temp.:

2-8°C

SMILES string:

CC(C)(C)[Si](C)(C)OCC=O

InChI:

1S/C8H18O2Si/c1-8(2,3)11(4,5)10-7-6-9/h6H,7H2,1-5H3

InChI key:

MEBFFOKESLAUSJ-UHFFFAOYSA-N

Sigma Aldrich

449504

Assay:

refractive index:

bp:

density:

storage temp.:

__

SMILES string:

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI:

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI key:

QSZMZKBZAYQGRS-UHFFFAOYSA-N

Sigma Aldrich

449504

Assay:

refractive index:

bp:

density:

storage temp.:

__

SMILES string:

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI:

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI key:

QSZMZKBZAYQGRS-UHFFFAOYSA-N

Sigma Aldrich

449520

97%...

Assay:

97%

refractive index:

bp:

density:

storage temp.:

SMILES string:

Cl[Ti].[CH]1[CH][CH][CH][CH]1.CC2(C)O[C@H]([C@@H](O2)C(O)(c3ccccc3)c4ccccc4)C(O)(c5ccccc5)c6ccccc6

InChI:

1S/C31H30O4.C5H5.ClH.Ti/c1-29(2)34-27(30(32,23-15-7-3-8-16-23)24-17-9-4-10-18-24)28(35-29)31(33,25-19-11-5-12-20-25)26-21-13-6-14-22-26;1-2-4-5-3-1;;/h3-22,27-28,32-33H,1-2H3;1-5H;1H;/q;;;+1/p-1/t27-,28-;;;/m1.../s1

InChI key:

LTNGUQMGXWBBMV-CRMRIEQBSA-M

(tert-Butyldimethylsilyloxy)acetaldehyde

Select a Size

Select a Size

Properties

Assay

refractive index

bp

density

storage temp.

SMILES string

InChI

InChI key

Other Options

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Sigma Aldrich

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Description

SAFETY INFORMATION

Pictograms

Signal Word

Hazard Statements

Precautionary Statements

Hazard Classifications

Target Organs

WGK

Flash Point(F)

Flash Point(C)

Personal Protective Equipment

Compare Similar Items

Show Difference

Sigma Aldrich

Assay: 90% refractive index: n20/D 1.432 (lit.) bp: 165-167 °C (lit.) density: 0.915 g/mL at 25 °C (lit.) storage temp.: 2-8°C SMILES string: CC(C)(C)[Si](C)(C)OCC=O InChI: 1S/C8H18O2Si/c1-8(2,3)11(4,5)10-7-6-9/h6H,7H2,1-5H3 InChI key: MEBFFOKESLAUSJ-UHFFFAOYSA-N

Sigma Aldrich

Assay: __ refractive index: __ bp: __ density: __ storage temp.: __ SMILES string: [Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F InChI: 1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1 InChI key: QSZMZKBZAYQGRS-UHFFFAOYSA-N

Sigma Aldrich

Assay: __ refractive index: __ bp: __ density: __ storage temp.: __ SMILES string: [Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F InChI: 1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1 InChI key: QSZMZKBZAYQGRS-UHFFFAOYSA-N

Sigma Aldrich

Assay:

90%

refractive index:

n20/D 1.432 (lit.)

bp:

165-167 °C (lit.)

density:

0.915 g/mL at 25 °C (lit.)

storage temp.:

2-8°C

SMILES string:

CC(C)(C)[Si](C)(C)OCC=O

InChI:

1S/C8H18O2Si/c1-8(2,3)11(4,5)10-7-6-9/h6H,7H2,1-5H3

InChI key:

MEBFFOKESLAUSJ-UHFFFAOYSA-N

Assay:

refractive index:

bp:

density:

storage temp.:

__

SMILES string:

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI:

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI key:

QSZMZKBZAYQGRS-UHFFFAOYSA-N

Assay:

refractive index:

bp:

density:

storage temp.:

__

SMILES string:

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI:

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI key:

QSZMZKBZAYQGRS-UHFFFAOYSA-N