494011

(4-Bromophenylethynyl)trimethylsilane

98%

Manufacturer: Sigma Aldrich

CAS Number: 16116-78-2

Synonym(S): (p-Bromophenyl)ethynyl)trimethylsilane, 1-(p-Bromophenyl)-2-trimethylsilylacetylene, 1-Bromo-4-(2-trimethylsilylethynyl)benzene, 1-Bromo-4-(trimethylsilylethynyl)benzene, 1-Bromo-4-[2-(trimethylsilyl)ethynyl]benzene, 2-(p-Bromophenyl)-1-trimethylsilylacetylene, 4-(Trimethylsilylethynyl)phenyl bromide, [(4-Bromophenyl)ethynyl]trimethylsilane, [1-(4-Bromophenyl)-2-trimethylsilyl]acetylene, [2-(4-Bromophenyl)ethynyl]trimethylsilane

Select a Size

Pack Size SKU Availability Price
5 G 494011-5-G In Stock ₹ 9,612.60
25 G 494011-25-G In Stock ₹ 11,799.25

494011 - 5 G

₹ 9,612.60

In Stock

Quantity

1

Base Price: ₹ 9,612.60

GST (18%): ₹ 1,730.268

Total Price: ₹ 11,342.868

Quality Level

100

Assay

98%

mp

61-63 °C (lit.)

SMILES string

C[Si](C)(C)C#Cc1ccc(Br)cc1

InChI

1S/C11H13BrSi/c1-13(2,3)9-8-10-4-6-11(12)7-5-10/h4-7H,1-3H3

InChI key

RNMSGCJGNJYDNS-UHFFFAOYSA-N

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Description

  • General description: (4-Bromophenylethynyl)trimethylsilane can be synthesized by the palladium catalyzed reaction between 4-bromo-1-iodobenzene and trimethylsilylacetylene.[1] It undergoes Buchwald-Hartwig coupling with para-substituted diphenylamines.[2]
  • Application: (4-Bromophenylethynyl)trimethylsilane may be used to synthesize:1-bromo-4-ethynylbenzene[1]4-(4-bromophenyl)-3-butyn-2-one[3]4-ethynyl-4′-tert-butylbiphenyl[4]1,4-bis[2-(4-bromophenyl)ethynyl]-2,5-dihexylbenzene[5]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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SMILES string:
C[Si](C)(C)C#Cc1ccc(Br)cc1

InChI:
1S/C11H13BrSi/c1-13(2,3)9-8-10-4-6-11(12)7-5-10/h4-7H,1-3H3

InChI key:
RNMSGCJGNJYDNS-UHFFFAOYSA-N

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