752150

Ethyl diazoacetate solution

15% in toluene

Manufacturer: Sigma Aldrich

CAS Number: 623-73-4

Synonym(S): 2-Diazoacetic acid ethyl ester solution

Select a Size

Pack Size SKU Availability Price
25 ML 752150-25-ML In Stock ₹ 3,474.83
100 ML 752150-100-ML In Stock ₹ 7,339.35

752150 - 25 ML

₹ 3,474.83

In Stock

Quantity

1

Base Price: ₹ 3,474.83

GST (18%): ₹ 625.469

Total Price: ₹ 4,100.299

form

liquid

Quality Level

100

concentration

15% in toluene

refractive index

n20/D 1.505

density

0.895 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCOC(=O)C=[N+]=[N-]

InChI

1S/C4H6N2O2/c1-2-8-4(7)3-6-5/h3H,2H2,1H3

InChI key

YVPJCJLMRRTDMQ-UHFFFAOYSA-N

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Description

  • General description: Ethyl diazoacetate solution is a diazo compound that is used as a reagent for the cyclopropanation of unsaturated compounds. It is used to prepare cyclopropane and cyclopropane carboxylic acid derivatives by catalytic decomposition of ethyl diazoacetate in the presence of alkenes. It is also a useful reagent for the homologation of cyclic and acyclic ketones without the formation of epoxides as byproducts.
  • Application: New Diazoacetate Formulations

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS07

Signal Word

Danger

Hazard Statements

H225,H304,H315,H336,H351,H361d,H373,H412

Precautionary Statements

P202 - P210 - P273 - P301 + P310 - P303 + P361 + P353 - P331

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

Target Organs

Central nervous system

WGK

WGK 3

Flash Point(F)

39.9 °F

Flash Point(C)

4.4 °C

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752150

15% in toluene...


form:
liquid

Quality Level:
100

concentration:
15% in toluene

refractive index:
n20/D 1.505

density:
0.895 g/mL at 25 °C

storage temp.:
2-8°C

SMILES string:
CCOC(=O)C=[N+]=[N-]

InChI:
1S/C4H6N2O2/c1-2-8-4(7)3-6-5/h3H,2H2,1H3

InChI key:
YVPJCJLMRRTDMQ-UHFFFAOYSA-N

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100

concentration:
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storage temp.:
2-8°C

SMILES string:
CC(C)(C)OC(=O)C=[N+]=[N-]

InChI:
1S/C6H10N2O2/c1-6(2,3)10-5(9)4-8-7/h4H,1-3H3

InChI key:
JBVSBLLOZVDAAZ-UHFFFAOYSA-N

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