805041

2-(trimethylsilyl)-2-cyclohexen-1-one

Manufacturer: Sigma Aldrich

CAS Number: 72162-99-3

Select a Size

Pack Size SKU Availability Price
500 MG 805041-500-MG In Stock ₹ 13,693.63

805041 - 500 MG

₹ 13,693.63

In Stock

Quantity

1

Base Price: ₹ 13,693.63

GST (18%): ₹ 2,464.853

Total Price: ₹ 16,158.483

description

Fp: 15.8°F

Quality Level

100

form

liquid

refractive index

n20/D 1.4524

density

0.8680 g/mL at 25 °C

storage temp.

−20°C

SMILES string

O=C1C([Si](C)(C)C)=CCCC1

InChI

1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3

InChI key

SXGCQSJRVVKTOH-UHFFFAOYSA-N

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Description

  • General description: 2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.
  • Application: The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.
  • Other Notes: Cycloadditions of Cyclohexynes and Cyclopentyne

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Warning

Hazard Statements

H228,H302

Precautionary Statements

P210 - P301 + P312 + P330 - P370 + P378

Hazard Classifications

Acute Tox. 4 Oral - Flam. Sol. 2

WGK

WGK 3

Flash Point(F)

15.8 °F

Flash Point(C)

-9 °C

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description:
Fp: 15.8°F

Quality Level:
100

form:
liquid

refractive index:
n20/D 1.4524

density:
0.8680 g/mL at 25 °C

storage temp.:
−20°C

SMILES string:
O=C1C([Si](C)(C)C)=CCCC1

InChI:
1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3

InChI key:
SXGCQSJRVVKTOH-UHFFFAOYSA-N

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