14694

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Manufacturer: Sigma Aldrich

CAS Number: 35138-22-8

Synonym(S): Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex

Select a Size

Pack Size SKU Availability Price
100 MG 14694-100-MG In Stock ₹ 5,050.50

14694 - 100 MG

₹ 5,050.50

In Stock

Quantity

1

Base Price: ₹ 5,050.50

GST (18%): ₹ 909.09

Total Price: ₹ 5,959.59

composition

carbon content, 45.7-49.0%

Quality Level

100

reaction suitability

core: rhodiumreagent type: catalyst

mp

~190 °C (dec.)

SMILES string

[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1/b2*2-1-,8-7-;;

InChI key

NBGSCPNNKGVTKU-QMDOQEJBSA-N

Other Options

Image Product Name Manufacturer Price Range
AR0039VS
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Aaron Chemicals LLC ₹ 1,625.64 - ₹ 48,683.64

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Description

  • Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
  • Other Notes: Rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation[1][2][3]; Hydrosilylation[4]

SAFETY INFORMATION

Pictograms

GHS08,GHS07

Signal Word

Danger

Hazard Statements

H302,H315,H317,H319,H334,H335

Precautionary Statements

P261 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Sigma Aldrich

14694

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composition:
carbon content, 45.7-49.0%

Quality Level:
100

reaction suitability:
core: rhodiumreagent type: catalyst

mp:
~190 °C (dec.)

SMILES string:
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI:
1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1/b2*2-1-,8-7-;;

InChI key:
NBGSCPNNKGVTKU-QMDOQEJBSA-N

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CC(=O)O[C@]1(CC[C@H]2[C@@H]3CCC4=CC(=O)CC[C@@H]4[C@H]3CC[C@]12C)C#C

InChI:
1S/C22H28O3/c1-4-22(25-14(2)23)12-10-20-19-7-5-15-13-16(24)6-8-17(15)18(19)9-11-21(20,22)3/h1,13,17-20H,5-12H2,2-3H3/t17-,18+,19+,20-,21-,22-/m0/s1

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IMONTRJLAWHYGT-ZCPXKWAGSA-N

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