223662
Tris(triphenylphosphine)ruthenium(II) dichloride
97%
Manufacturer: Sigma Aldrich
CAS Number: 15529-49-4
Synonym(S): Tris(triphenylphosphine)dichlororuthenium, Dichlorotris(triphenylphosphine)ruthenium(II), Ruthenium(II)-tris(triphenylphosphine) dichloride
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 223662-1-G | In Stock | ₹ 3,930.00 |
| 5 G | 223662-5-G | In Stock | ₹ 14,950.00 |
| 25 G | 223662-25-G | In Stock | ₹ 73,415.40 |
223662 - 1 G
In Stock
Quantity
1
Base Price: ₹ 3,930.00
GST (18%): ₹ 707.40
Total Price: ₹ 4,637.40
Quality Level
100
Assay
97%
reaction suitability
core: rutheniumreagent type: catalystreaction type: C-H Activation
SMILES string
Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChI key
WIWBLJMBLGWSIN-UHFFFAOYSA-L
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Accela Chembio Inc Tris(triphenylphosphine)ruthenium(ii) Dichloride | 25g | 15529-49-4 | MFCD00013077 | 97+% | Shelf Life: 900 Days | Moisture Sensitive/n2/+4 | Accela Chembio Inc | ₹ 9,753.84 | |
 | Sigma Aldrich Fine Chemicals Biosciences Tris(triphenylphosphine)ruthenium(II) dichloride 97% | 15529-49-4 | MFCD00013077 | 5G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 18,551.97 | |
 | Chemscene AbaChemscene,tris(Triphenylphosphoranyl)ruthenium(V) chloride,15529-49-4,Formula:C54H45Cl2P3Ru,M. Wt. 958.85,>99.0% | Chemscene | ₹ 9,839.40 |
Related Products
Description
- Application: Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl2(PPh3)3] can be used as a catalyst to synthesize: Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp3 C-H bond activation of primary alcohols in the presence of Lewis acid.[1]Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.[2] 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.[3] Vinyl chloride monomer by hydrochlorination reaction of acetylene.[4]RuCl2(PPh3)3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.[3]
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 97%
reaction suitability: core: rutheniumreagent type: catalystreaction type: C-H Activation
SMILES string: Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI: 1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChI key: WIWBLJMBLGWSIN-UHFFFAOYSA-L
Quality Level:
100
Assay:
97%
reaction suitability:
core: rutheniumreagent type: catalystreaction type: C-H Activation
SMILES string:
Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI:
1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChI key:
WIWBLJMBLGWSIN-UHFFFAOYSA-L
Quality Level: 100
Assay: 95%
reaction suitability: core: zirconiumreagent type: catalystreagent type: reductant
SMILES string: [H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI: 1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1
InChI key: PSYHEBZUPSHSKK-UHFFFAOYSA-M
Quality Level:
100
Assay:
95%
reaction suitability:
core: zirconiumreagent type: catalystreagent type: reductant
SMILES string:
[H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI:
1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1
InChI key:
PSYHEBZUPSHSKK-UHFFFAOYSA-M
Quality Level: 100
Assay: 95%
reaction suitability: core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst
SMILES string: Cl[Pd]Cl.N#Cc1ccccc1.N#Cc2ccccc2
InChI: 1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI key: __
Quality Level:
100
Assay:
95%
reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst
SMILES string:
Cl[Pd]Cl.N#Cc1ccccc1.N#Cc2ccccc2
InChI:
1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
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