232734

R-Alpine-Borane® solution

0.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 73624-47-2

Synonym(S): B-Isopinocampheyl-9-borabicyclo[3.3.1]nonane solution

Select a Size

Pack Size SKU Availability Price
100 ML 232734-100-ML In Stock ₹ 15,793.68

232734 - 100 ML

₹ 15,793.68

In Stock

Quantity

1

Base Price: ₹ 15,793.68

GST (18%): ₹ 2,842.862

Total Price: ₹ 18,636.542

form

liquid

Quality Level

100

optical activity

[α]20/D −3.0°, neat

concentration

0.5 M in THF

density

0.896 g/mL at 25 °C

SMILES string

C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B3[C@@H]4CCC[C@H]3CCC4

InChI

1S/C18H31B/c1-12-16-10-13(18(16,2)3)11-17(12)19-14-6-4-7-15(19)9-5-8-14/h12-17H,4-11H2,1-3H3/t12-,13+,14-,15+,16-,17-/m1/s1

InChI key

VCDGSBJCRYTLNU-PHPOFCCKSA-N

Other Options

Image Product Name Manufacturer Price Range
AH15702
73624-47-2 | 9-(2,6,6-Trimethylbicyclo[3.1.1]hept-3-yl)-9-borabicyclo[3.3.1]nonane
A2B Chem --

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Description

  • General description: R-Alpine-Borane® is a chiral reducing agent, synthesized from (+)-α-pinene via hydroboration.[1][2]
  • Application: R- and S-Alpine-Boranes are used for asymmetric reduction of aldehydes[3][4] and prochiral ketones.[5][6][4]
  • Legal Information: Alpine-Borane is a registered trademark of Merck KGaA, Darmstadt, Germany

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS07

Signal Word

Danger

Hazard Statements

H225,H302,H315,H319,H335,H336,H351

Precautionary Statements

P202 - P210 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 3

Flash Point(F)

1.4 °F

Flash Point(C)

-17 °C

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Show Difference

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Sigma Aldrich

232734

0.5 M in THF...


form:
liquid

Quality Level:
100

optical activity:
[α]20/D −3.0°, neat

concentration:
0.5 M in THF

density:
0.896 g/mL at 25 °C

SMILES string:
C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B3[C@@H]4CCC[C@H]3CCC4

InChI:
1S/C18H31B/c1-12-16-10-13(18(16,2)3)11-17(12)19-14-6-4-7-15(19)9-5-8-14/h12-17H,4-11H2,1-3H3/t12-,13+,14-,15+,16-,17-/m1/s1

InChI key:
VCDGSBJCRYTLNU-PHPOFCCKSA-N

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__

concentration:
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1.143 g/mL at 25 °C (lit.)

SMILES string:
OCCSc1ccccc1

InChI:
1S/C8H10OS/c9-6-7-10-8-4-2-1-3-5-8/h1-5,9H,6-7H2

InChI key:
KWWZHCSQVRVQGF-UHFFFAOYSA-N

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powder

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7.16 g/mL at 25 °C (lit.)

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O=[W](=O)=O

InChI:
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InChI key:
ZNOKGRXACCSDPY-UHFFFAOYSA-N

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Sigma Aldrich

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form:
powder

Quality Level:
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optical activity:
__

concentration:
__

density:
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SMILES string:
[H]C(=O)c1cccc(c1)C(O)=O

InChI:
1S/C8H6O3/c9-5-6-2-1-3-7(4-6)8(10)11/h1-5H,(H,10,11)

InChI key:
UHDNUPHSDMOGCR-UHFFFAOYSA-N