275891

Dichloro(1,5-cyclooctadiene)palladium(II)

99%

Manufacturer: Sigma Aldrich

CAS Number: 12107-56-1

Synonym(S): PdCl2(cod)

Select a Size

Pack Size SKU Availability Price
2 G 275891-2-G In Stock ₹ 20,967.90

275891 - 2 G

₹ 20,967.90

In Stock

Quantity

1

Base Price: ₹ 20,967.90

GST (18%): ₹ 3,774.222

Total Price: ₹ 24,742.122

Quality Level

100

Assay

99%

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp

210 °C (dec.) (lit.)

SMILES string

Cl[Pd]Cl.C1CC=CCCC=C1

InChI

1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;

InChI key

RRHPTXZOMDSKRS-PHFPKPIQSA-L

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Description

  • Application: Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation.[1][2] It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes[3]; the synthesis of benzo[b]thiophenes from thioenols[4] and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.[5]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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275891

99%...


Quality Level:
100

Assay:
99%

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp:
210 °C (dec.) (lit.)

SMILES string:
Cl[Pd]Cl.C1CC=CCCC=C1

InChI:
1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;

InChI key:
RRHPTXZOMDSKRS-PHFPKPIQSA-L

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Sigma Aldrich

275905

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Assay:
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core: platinumreagent type: catalyst

mp:
__

SMILES string:
N.N.N.N.O.Cl[Pt]Cl

InChI:
1S/2ClH.4H3N.H2O.Pt/h2*1H;4*1H3;1H2;/q;;;;;;;+2/p-2

InChI key:
GWBDNMCYHWRSOH-UHFFFAOYSA-L

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mp:
__

SMILES string:
CSc1ccc(C)cc1

InChI:
1S/C8H10S/c1-7-3-5-8(9-2)6-4-7/h3-6H,1-2H3

InChI key:
VHILIAIEEYLJNA-UHFFFAOYSA-N

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Sigma Aldrich

27597

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Assay:
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reaction suitability:
__

mp:
__

SMILES string:
COC1=C(OC)C(=O)C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(\C)C)=C(C)C1=O

InChI:
1S/C54H82O4/c1-40(2)22-14-23-41(3)24-15-25-42(4)26-16-27-43(5)28-17-29-44(6)30-18-31-45(7)32-19-33-46(8)34-20-35-47(9)36-21-37-48(10)38-39-50-49(11)51(55)53(57-12)54(58-13)52(50)56/h22,24,26,28,30,32,34,36,38H,14-21,23,25,27,29,31,33,35,37,39H2,1-13H3/b41-24+,42-26+,43-28+,44-30+,45-32+,46-34+,47-36+,48-38+

InChI key:
UUGXJSBPSRROMU-WJNLUYJISA-N