276286

(1R)-(−)-Camphorquinone

99%

Manufacturer: Sigma Aldrich

CAS Number: 10334-26-6

Synonym(S): (1R)-(−)-2,3-Bornanedione, 2,3-Bornanedione

Select a Size

Pack Size SKU Availability Price
5 G 276286-5-G In Stock ₹ 16,832.88

276286 - 5 G

₹ 16,832.88

In Stock

Quantity

1

Base Price: ₹ 16,832.88

GST (18%): ₹ 3,029.918

Total Price: ₹ 19,862.798

Quality Level

100

Assay

99%

optical activity

[α]20/D −101°, c = 2 in toluene

mp

200-203 °C (lit.)

SMILES string

CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O

InChI

1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1

InChI key

VNQXSTWCDUXYEZ-LDWIPMOCSA-N

Other Options

Image Product Name Manufacturer Price Range
CS-0179388
(1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione
ChemScene ₹ 10,352.76
AB54657
10334-26-6 | (1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione
A2B Chem ₹ 1,283.40 - ₹ 20,448.84

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Description

  • Application: (1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of: α-Hydroxycamphors by selective reduction of keto groups using various vegetables.[1] Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.[2] Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.[3] Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.[4]

SAFETY INFORMATION

Pictograms

GHS08,GHS07

Signal Word

Danger

Hazard Statements

H302,H334

Precautionary Statements

P261 - P264 - P270 - P284 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral - Resp. Sens. 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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optical activity:
[α]20/D −101°, c = 2 in toluene

mp:
200-203 °C (lit.)

SMILES string:
CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O

InChI:
1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1

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VNQXSTWCDUXYEZ-LDWIPMOCSA-N

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