trans-1,2-Bis(diphenylphosphino)ethylene
97%
Manufacturer: Sigma Aldrich
CAS Number: 983-81-3
Synonym(S): (E)-Vinylenebis[diphenylphosphine], trans-1,2-Ethenediylbis(diphenylphosphine), NSC 132587
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 287970-1-G | In Stock | ₹ 3,842.88 |
287970 - 1 G
In Stock
Quantity
1
Base Price: ₹ 3,842.88
GST (18%): ₹ 691.718
Total Price: ₹ 4,534.598
Quality Level
100
Assay
97%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand
mp
126-130 °C (lit.)
functional group
phosphine
SMILES string
c1ccc(cc1)P(\C=C\P(c2ccccc2)c3ccccc3)c4ccccc4
InChI
1S/C26H22P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-22H/b22-21+
InChI key
NCKJIJSEWKIXAT-QURGRASLSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | 983-81-3 | (E)-1,2-Bis(diphenylphosphino)ethene | A2B Chem | ₹ 2,737.92 - ₹ 82,137.60 |
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Description
- Application: Catalyst for:Coupling of primary and secondary alkyl halides with aryl grignard reagentsHomogeneous hydrogenation of Carbon Dioxide mediated by RutheniumReactant for:Preparation of cyclopalladated derivatives of benzylidenePreparation of cyclopalladated complexes containing tridentate thiosemicarbazone ligands as antimalarial agentsCatalytic asymetric intramolecular hydroamination of alkynylamines
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Quality Level: 100
Assay: 97%
reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand
mp: 126-130 °C (lit.)
functional group: phosphine
SMILES string: c1ccc(cc1)P(\C=C\P(c2ccccc2)c3ccccc3)c4ccccc4
InChI: 1S/C26H22P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-22H/b22-21+
InChI key: NCKJIJSEWKIXAT-QURGRASLSA-N
Quality Level: 100
Assay: 97%
reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand
mp: 124-126 °C (lit.)
functional group: phosphine
SMILES string: C(CCCP(c1ccccc1)c2ccccc2)CCP(c3ccccc3)c4ccccc4
InChI: 1S/C30H32P2/c1(15-25-31(27-17-7-3-8-18-27)28-19-9-4-10-20-28)2-16-26-32(29-21-11-5-12-22-29)30-23-13-6-14-24-30/h3-14,17-24H,1-2,15-16,25-26H2
InChI key: GPORFKPYXATYNX-UHFFFAOYSA-N
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