317020

(−)-DIP-Chloride™

Manufacturer: Sigma Aldrich

CAS Number: 85116-37-6

Synonym(S): (−)-B-Chlorodiisopinocampheylborane, (−)-Ipc2BCl

Select a Size

Pack Size SKU Availability Price
5 G 317020-5-G In Stock ₹ 14,711.18
25 G 317020-25-G In Stock ₹ 34,596.70
100 G 317020-100-G In Stock ₹ 46,579.98

317020 - 5 G

₹ 14,711.18

In Stock

Quantity

1

Base Price: ₹ 14,711.18

GST (18%): ₹ 2,648.012

Total Price: ₹ 17,359.192

form

solid

Quality Level

100

mp

52-56 °C (lit.)

SMILES string

C[C@H]1[C@@H](CC2CCC1C2(C)C)B(Cl)[C@@H]3CC4CCC([C@H]3C)C4(C)C

InChI

1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m1/s1

InChI key

PSEHHVRCDVOTID-VMAIWCPRSA-N

Other Options

Image Product Name Manufacturer Price Range
NC2045286
eMolecules​ Chlorobis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane | 85116-37-6 | MFCD23136838 | 25g
eMolecules​ ₹ 22,166.03
648418
(−)-DIP-Chloride™ solution
Sigma Aldrich ₹ 17,352.48 - ₹ 22,667.55
AB42747
85116-37-6 | (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L)
A2B Chem ₹ 26,181.36 - ₹ 82,736.52

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Description

  • Application: Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones[1][2] and for the preparation of β-amino alcohols.[2][3]
  • Legal Information: DIP-Chloride is a trademark of Sigma-Aldrich Co. LLC

SAFETY INFORMATION

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Sigma Aldrich

317020

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form:
solid

Quality Level:
100

mp:
52-56 °C (lit.)

SMILES string:
C[C@H]1[C@@H](CC2CCC1C2(C)C)B(Cl)[C@@H]3CC4CCC([C@H]3C)C4(C)C

InChI:
1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m1/s1

InChI key:
PSEHHVRCDVOTID-VMAIWCPRSA-N

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Fischer Scientific

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COB([C@H]1CC2CC([C@@H]1C)C2(C)C)[C@H]3CC4CC([C@@H]3C)C4(C)C

InChI:
1S/C21H37BO/c1-12-16-8-14(20(16,3)4)10-18(12)22(23-7)19-11-15-9-17(13(19)2)21(15,5)6/h12-19H,8-11H2,1-7H3/t12-,13-,14+,15+,16-,17-,18-,19-/m0/s1

InChI key:
IAQXEQYLQNNXJC-JPDDNCELSA-N