345350

(1S)-(+)-(10-Camphorsulfonyl)oxaziridine

Manufacturer: Sigma Aldrich

CAS Number: 104322-63-6

Synonym(S): (1S)-(+)-(Camphorylsulfonyl)oxaziridine, (1S)-(+)-2,N-Epoxy-exo-10,2-bornanesultam

Select a Size

Pack Size SKU Availability Price
1 G 345350-1-G In Stock ₹ 6,679.03

345350 - 1 G

₹ 6,679.03

In Stock

Quantity

1

Base Price: ₹ 6,679.03

GST (18%): ₹ 1,202.225

Total Price: ₹ 7,881.255

form

solid

Quality Level

200

optical activity

[α]28/D +45°, c = 2 in chloroform

impurities

<1% toluene

mp

172-174 °C (lit.)

storage temp.

2-8°C

SMILES string

CC1(C)[C@@H]2CC[C@]13CS(=O)(=O)N4O[C@@]34C2

InChI

1S/C10H15NO3S/c1-8(2)7-3-4-9(8)6-15(12,13)11-10(9,5-7)14-11/h7H,3-6H2,1-2H3/t7-,9+,10+,11?/m1/s1

InChI key

GBBJBUGPGFNISJ-YDQXZVTASA-N

Other Options

Image Product Name Manufacturer Price Range
AB54668
104322-63-6 | (1S)-(+)-(10-Camphorsulfonyl)oxaziridine
A2B Chem ₹ 427.80 - ₹ 9,326.04

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Description

  • Application: (1S)-(+)-(10-Camphorsulfonyl)oxaziridine can be used:To convert prochiral ketone enolates into optically active α-hydroxy ketones via enantioselective asymmetric oxidation.[1]In the synthesis of thymidine oligonucleotides connected through pyrophosphates.[2]In the asymmetric synthesis of proton pump inhibitors like (R)-Rabeprazole sodium and (R)-Lansoprazole sodium from the corresponding DBU salt of prochiral sulfide.[3]In the preparation of phosphonoacetate and thiophosphonoacetate oligodeoxynucleotides by oxidizing the corresponding phosphinoacetate.[4]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

345350

--


form:
solid

Quality Level:
200

optical activity:
[α]28/D +45°, c = 2 in chloroform

impurities:
<1% toluene

mp:
172-174 °C (lit.)

storage temp.:
2-8°C

SMILES string:
CC1(C)[C@@H]2CC[C@]13CS(=O)(=O)N4O[C@@]34C2

InChI:
1S/C10H15NO3S/c1-8(2)7-3-4-9(8)6-15(12,13)11-10(9,5-7)14-11/h7H,3-6H2,1-2H3/t7-,9+,10+,11?/m1/s1

InChI key:
GBBJBUGPGFNISJ-YDQXZVTASA-N

Img

Sigma Aldrich

345415

98%...


form:
liquid

Quality Level:
100

optical activity:
__

impurities:
__

mp:
__

storage temp.:
__

SMILES string:
CON(C)C(=O)c1ccccc1

InChI:
1S/C9H11NO2/c1-10(12-2)9(11)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI key:
UKERDACREYXSIV-UHFFFAOYSA-N

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Sigma Aldrich

345458

1.0 M in p-xylene...


form:
liquid

Quality Level:
200

optical activity:
__

impurities:
__

mp:
__

storage temp.:
__

SMILES string:
ClB(Cl)Cl

InChI:
1S/BCl3/c2-1(3)4

InChI key:
FAQYAMRNWDIXMY-UHFFFAOYSA-N

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Sigma Aldrich

345474

95%...


form:
liquid

Quality Level:
100

optical activity:
__

impurities:
__

mp:
__

storage temp.:
__

SMILES string:
[Li+].C[Si](C)(C)[O-]

InChI:
1S/C3H9OSi.Li/c1-5(2,3)4;/h1-3H3;/q-1;+1

InChI key:
OXOZHAWWRPCVGL-UHFFFAOYSA-N