407240

Copper(I) trifluoromethanesulfonate benzene complex

technical grade, 90%

Manufacturer: Sigma Aldrich

CAS Number: 42152-46-5

Synonym(S): Copper(I) triflate benzene complex, Cuprous trifluoromethanesulfonate benzene complex, Trifluoromethanesulfonic acid copper(I) salt benzene complex

Select a Size

Pack Size SKU Availability Price
1 G 407240-1-G In Stock ₹ 5,443.80
5 G 407240-5-G In Stock ₹ 8,281.75

407240 - 1 G

₹ 5,443.80

In Stock

Quantity

1

Base Price: ₹ 5,443.80

GST (18%): ₹ 979.884

Total Price: ₹ 6,423.684

grade

technical grade

Quality Level

100

Assay

90%

form

powder

reaction suitability

core: copperreagent type: catalyst

mp

160 °C (dec.) (lit.)

SMILES string

[Cu+].[Cu+].c1ccccc1.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/C6H6.2CHF3O3S.2Cu/c1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;;/h1-6H;2*(H,5,6,7);;/q;;;2*+1/p-2

InChI key

GNXZWVVAAMVOJY-UHFFFAOYSA-L

Other Options

Image Product Name Manufacturer Price Range
50-243-9318
eMolecules​ Ambeed / Copper(I) trifluoromethanesulfonate benzene complex / 1g / 572824836 / A426791 / / 42152-46-5 / MFCD00043300 / 503.330 / C8H6Cu2F6O6S2
eMolecules​ ₹ 4,031.59
AR003PR0
COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
Aaron Chemicals LLC ₹ 342.24 - ₹ 1,08,917.88
AB72240
42152-46-5 | Copper(I) trifluoromethanesulfonate benzene complex
A2B Chem ₹ 598.92 - ₹ 7,187.04

Related Products

Img

Sigma Aldrich

442151

--

Img

Sigma Aldrich

430609

99.999% trace metals basis...

Img

Sigma Aldrich

405345

98%...

Img

Sigma Aldrich

425672

98%...

Img

Sigma Aldrich

405329

Yb 25-28 % (approx.)...

Img

Sigma Aldrich

425699

98%...

Img

Sigma Aldrich

346276

97%...

Img

Sigma Aldrich

C87851

97%...

Description

  • Application: Copper(I) trifluoromethanesulfonate benzene complex can be used as a catalyst: To synthesize enol-esters via copper(I) carboxylate intermediate formation.[1] In the enantioselective allylic oxidation of cyclic alkenes.[2] To prepare 2,5-disubstituted pyrrolidine derivatives from N-alkenyl, alkynyl and alkyl N-benzoyloxysulfonamides via the sulfonamidyl radical formation.[3] It can also be used in combination with amino acid-based chiral phosphine ligands to catalyze asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity.[4]

SAFETY INFORMATION

Pictograms

GHS02

Signal Word

Warning

Hazard Statements

H228

Precautionary Statements

P210 - P240 - P241 - P280 - P370 + P378

Hazard Classifications

Flam. Sol. 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

407240

technical grade, 90%...


grade:
technical grade

Quality Level:
100

Assay:
90%

form:
powder

reaction suitability:
core: copperreagent type: catalyst

mp:
160 °C (dec.) (lit.)

SMILES string:
[Cu+].[Cu+].c1ccccc1.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI:
1S/C6H6.2CHF3O3S.2Cu/c1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;;/h1-6H;2*(H,5,6,7);;/q;;;2*+1/p-2

InChI key:
GNXZWVVAAMVOJY-UHFFFAOYSA-L

Img

Sigma Aldrich

40725

absolute, over molecular sieve (H2O...


grade:
absolute

Quality Level:
200

Assay:
≥99.5% (GC)

form:
liquid

reaction suitability:
__

mp:
__

SMILES string:
CN1CCN(C)C1=O

InChI:
__

InChI key:
__

Img

Fischer Scientific

4072664

Thermo Scientific GeneJET FFPE DNA ...


grade:
__

Quality Level:
__

Assay:
__

form:
__

reaction suitability:
__

mp:
__

SMILES string:
__

InChI:
__

InChI key:
__

Img

Sigma Aldrich

407267

purified by redistillation, ≥99.5%...


grade:
__

Quality Level:
100

Assay:
≥99.5%

form:
liquid

reaction suitability:
__

mp:
__

SMILES string:
NCCc1ccccc1

InChI:
1S/C8H11N/c9-7-6-8-4-2-1-3-5-8/h1-5H,6-7,9H2

InChI key:
__