420964
(1S)-(+)-Ketopinic acid
99%
Manufacturer: Sigma Aldrich
CAS Number: 40724-67-2
Synonym(S): (1S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 420964-1-G | In Stock | ₹ 6,740.00 |
420964 - 1 G
In Stock
Quantity
1
Base Price: ₹ 6,740.00
GST (18%): ₹ 1,213.20
Total Price: ₹ 7,953.20
Assay
99%
optical activity
[α]23/D +58°, c = 1 in chloroform
mp
237-239 °C (lit.)
SMILES string
CC1(C)C2CCC1(C(O)=O)C(=O)C2
InChI
1S/C10H14O3/c1-9(2)6-3-4-10(9,8(12)13)7(11)5-6/h6H,3-5H2,1-2H3,(H,12,13)/t6-,10+/m1/s1
InChI key
WDODWBQJVMBHCO-LDWIPMOCSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules Ambeed / (S)-()-Ketopinic Acid / 100mg / 627733369 / A169658 / / 40724-67-2 / [null] / 182.219 / C10H14O3 | eMolecules | ₹ 2,065.42 | |
 | (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid | Aaron Chemicals LLC | ₹ 427.80 - ₹ 38,074.20 | |
 | (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid | ChemScene | ₹ 855.60 - ₹ 15,914.16 | |
 | 40724-67-2 | 7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid | A2B Chem | ₹ 427.80 - ₹ 87,442.32 |
Related Products
Description
- General description: (1S)-(+)-Ketopinic acid is a chiral ketone.[1]
- Application: (1S)-(+)-Ketopinic acid may be used to prepare:Chiral phosphine-oxazoline ligands, which can used in asymmetric palladium-catalyzed Heck reaction of aryl or alkenyl triflates with cyclic alkenes.[1]A chiral imino-phosphine ligand, which can be used in palladium-catalyzed asymmetric Diels–Alder reactions to prepare six-membered carbocycles.[2]A chiral iminopyridine ligand, which can be used in copper-catalyzed Henry (nitro aldol) reaction between nitromethane and o-anisol to form the corresponding β-hydroxynitroalkane.[3]
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Assay: 99%
optical activity: [α]23/D +58°, c = 1 in chloroform
mp: 237-239 °C (lit.)
SMILES string: CC1(C)C2CCC1(C(O)=O)C(=O)C2
InChI: 1S/C10H14O3/c1-9(2)6-3-4-10(9,8(12)13)7(11)5-6/h6H,3-5H2,1-2H3,(H,12,13)/t6-,10+/m1/s1
InChI key: WDODWBQJVMBHCO-LDWIPMOCSA-N
Assay:
99%
optical activity:
[α]23/D +58°, c = 1 in chloroform
mp:
237-239 °C (lit.)
SMILES string:
CC1(C)C2CCC1(C(O)=O)C(=O)C2
InChI:
1S/C10H14O3/c1-9(2)6-3-4-10(9,8(12)13)7(11)5-6/h6H,3-5H2,1-2H3,(H,12,13)/t6-,10+/m1/s1
InChI key:
WDODWBQJVMBHCO-LDWIPMOCSA-N
Assay: ≥98.0% (sum of enantiomers, HPLC)≥98.0%
optical activity: [α]20/D −14.0±1.5°, c = 2% in acetone
mp: 173-177 °C
SMILES string: __
InChI: __
InChI key: __
Assay:
≥98.0% (sum of enantiomers, HPLC)≥98.0%
optical activity:
[α]20/D −14.0±1.5°, c = 2% in acetone
mp:
173-177 °C
SMILES string:
__
InChI:
__
InChI key:
__
Assay: __
optical activity: __
mp: −11 °C (lit.)
SMILES string: CCCCOCCOCCOC(=O)CCCCC(=O)OCCOCCOCCCC
InChI: 1S/C22H42O8/c1-3-5-11-25-13-15-27-17-19-29-21(23)9-7-8-10-22(24)30-20-18-28-16-14-26-12-6-4-2/h3-20H2,1-2H3
InChI key: SCABKEBYDRTODC-UHFFFAOYSA-N
Assay:
__
optical activity:
__
mp:
−11 °C (lit.)
SMILES string:
CCCCOCCOCCOC(=O)CCCCC(=O)OCCOCCOCCCC
InChI:
1S/C22H42O8/c1-3-5-11-25-13-15-27-17-19-29-21(23)9-7-8-10-22(24)30-20-18-28-16-14-26-12-6-4-2/h3-20H2,1-2H3
InChI key:
SCABKEBYDRTODC-UHFFFAOYSA-N
Assay: ≥98.0% (sum of enantiomers, HPLC)≥98.0%
optical activity: [α]20/D +14.0±1.5°, c = 2% in acetone
mp: 173-177 °C (lit.)173-177 °C
SMILES string: CC(C)[C@H](Nc1cc(F)c(cc1[N+]([O-])=O)[N+]([O-])=O)C(N)=O
InChI: __
InChI key: __
Assay:
≥98.0% (sum of enantiomers, HPLC)≥98.0%
optical activity:
[α]20/D +14.0±1.5°, c = 2% in acetone
mp:
173-177 °C (lit.)173-177 °C
SMILES string:
CC(C)[C@H](Nc1cc(F)c(cc1[N+]([O-])=O)[N+]([O-])=O)C(N)=O
InChI:
__
InChI key:
__