Chlorocyclopentadienyl[(4R,5R)-2,2-dimethyl-α,α,α′,α′-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium
97%
Manufacturer: Sigma Aldrich
CAS Number: 132068-98-5
Synonym(S): (4R,5R)-Chloro-cyclopentadienyl-[2,2-dimethyl-1,3-dioxolan-4,5-bis(diphenylmethoxy)]titanium, (R,R)-Duthaler-Hafner reagent, [(4R,5R)-2,2-Dimethyl-1,3-dioxolan-4,5-bis(diphenylmethoxy)]cyclopentadienyl-chlorotitanium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 449520-100-MG | In Stock | ₹ 4,319.18 |
449520 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 4,319.18
GST (18%): ₹ 777.452
Total Price: ₹ 5,096.632
Quality Level
200
Assay
97%
optical activity
[α]20/D -246°, c = 1 in chloroform
mp
209-213 °C (lit.)
SMILES string
Cl[Ti].[CH]1[CH][CH][CH][CH]1.CC2(C)O[C@H]([C@@H](O2)C(O)(c3ccccc3)c4ccccc4)C(O)(c5ccccc5)c6ccccc6
InChI
1S/C31H30O4.C5H5.ClH.Ti/c1-29(2)34-27(30(32,23-15-7-3-8-16-23)24-17-9-4-10-18-24)28(35-29)31(33,25-19-11-5-12-20-25)26-21-13-6-14-22-26;1-2-4-5-3-1;;/h3-22,27-28,32-33H,1-2H3;1-5H;1H;/q;;;+1/p-1/t27-,28-;;;/m1.../s1
InChI key
LTNGUQMGXWBBMV-CRMRIEQBSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences Chlorocyclopentadienyl[(4R,5R)-2,2-dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium 97% | 132068-98-5 | 100MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 8,162.42 | |
 | 132068-98-5 | Chlorocyclopentadienyl[(4R,5R)-2,2-dimethyl-α,α,α′,α′-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium | A2B Chem | -- |
Related Products
Description
- Application: A novel highly enantioselective allyl-transfer reagent. Excellent regio-, diastereo-, and enantioselectivities (usually >95% ee, >95% de) are obtained for the addition of allyl nucleophiles to aldehydes.[1][2][3][4] Although this reagent is used in stoichiometric amounts, the chiral ligand and monocyclopentadienyltitanium trichloride can be easily recovered.[5]
- Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
Hazard Classifications
Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 200
Assay: 97%
optical activity: [α]20/D -246°, c = 1 in chloroform
mp: 209-213 °C (lit.)
SMILES string: Cl[Ti].[CH]1[CH][CH][CH][CH]1.CC2(C)O[C@H]([C@@H](O2)C(O)(c3ccccc3)c4ccccc4)C(O)(c5ccccc5)c6ccccc6
InChI: 1S/C31H30O4.C5H5.ClH.Ti/c1-29(2)34-27(30(32,23-15-7-3-8-16-23)24-17-9-4-10-18-24)28(35-29)31(33,25-19-11-5-12-20-25)26-21-13-6-14-22-26;1-2-4-5-3-1;;/h3-22,27-28,32-33H,1-2H3;1-5H;1H;/q;;;+1/p-1/t27-,28-;;;/m1.../s1
InChI key: LTNGUQMGXWBBMV-CRMRIEQBSA-M
Quality Level: 100
Assay: ≥98.0% (dried material)
optical activity: __
mp: __
SMILES string: O.CC(O)C(=O)O[Fe]OC(=O)C(C)O
InChI: 1S/2C3H6O3.Fe.H2O/c2*1-2(4)3(5)6;;/h2*2,4H,1H3,(H,5,6);;1H2/q;;+2;/p-2
InChI key: FDSNKEJXJCZFLE-UHFFFAOYSA-L
Quality Level: __
Assay: __
optical activity: __
mp: __
SMILES string: __
InChI: __
InChI key: __
