569755

Hoveyda-Grubbs Catalyst® M720

Umicore, 97%

Manufacturer: Sigma Aldrich

CAS Number: 301224-40-8

Synonym(S): Hoveyda-Grubbs Catalyst® 2nd Generation, Hoveyda-Grubbs Catalyst® M72 (C627), (1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium, Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II), Grubbs Catalyst® C627

Select a Size

Pack Size SKU Availability Price
100 MG 569755-100-MG In Stock ₹ 5,710.00
500 MG 569755-500-MG In Stock ₹ 31,612.80
2 G 569755-2-G In Stock ₹ 70,185.30
10 G 569755-10-G In Stock ₹ 2,43,567.30
25 G 569755-25-G In Stock ₹ 4,87,789.50

569755 - 100 MG

₹ 5,710.00

In Stock

Quantity

1

Base Price: ₹ 5,710.00

GST (18%): ₹ 1,027.80

Total Price: ₹ 6,737.80

Quality Level

100

Assay

97%

form

solid

reaction suitability

core: rutheniumreagent type: catalystreaction type: Ring-Opening Polymerization

mp

216-220 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3c(C)cc(C)cc3C)c4c(C)cc(C)cc4C

InChI

1S/C21H26N2.C10H12O.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-8(2)11-10-7-5-4-6-9(10)3;;;/h9-12H,7-8H2,1-6H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2

InChI key

ZRPFJAPZDXQHSM-UHFFFAOYSA-L

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Description

  • Application: It′s a phosphine free version of Grubbs 2nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient for metathesis of electron-deficient substrates including fluorinated olefins. Demonstrated in multiple large-scale pharmaceutical applications.It can be used as a catalyst for olefin cross-metathesis with fluorinated olefins (CM),[1] ring-closing metathesis (RCM),[2] ring-opening metathesis (ROM),[3] and a sequence of a metathesis reaction and subsequent dihydroxylation of the newly formed double bond.[4]Learn more about our metathesis catalysts
  • Other Notes: Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich
  • Legal Information: Product of UmicoreProduct LicenseThis product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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CC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3c(C)cc(C)cc3C)c4c(C)cc(C)cc4C

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ZRPFJAPZDXQHSM-UHFFFAOYSA-L

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