638099

CyJohnPhos

97%

Manufacturer: Sigma Aldrich

CAS Number: 247940-06-3

Synonym(S): 2-(Dicyclohexylphosphino)biphenyl, (2-Biphenyl)dicyclohexylphosphine, Cyclohexyl JohnPhos

Select a Size

Pack Size SKU Availability Price
1 G 638099-1-G In Stock ₹ 5,090.00
5 G 638099-5-G In Stock ₹ 13,444.65
25 G 638099-25-G In Stock ₹ 62,189.63

638099 - 1 G

₹ 5,090.00

In Stock

Quantity

1

Base Price: ₹ 5,090.00

GST (18%): ₹ 916.20

Total Price: ₹ 6,006.20

Quality Level

100

Assay

97%

reaction suitability

reaction type: Cross Couplingsreagent type: ligandreaction type: Arylationsreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: C-X Bond Formationreagent type: ligandreaction type: Hiyama Couplingreagent type: ligandreaction type: Methylationsreagent type: ligandreaction type: Negishi Couplingreagent type: ligandreaction type: Oxidationsreagent type: ligandreaction type: Suzuki-Miyaura Coupling

mp

102-106 °C (lit.)

functional group

phosphine

SMILES string

C1CCC(CC1)P(C2CCCCC2)c3ccccc3-c4ccccc4

InChI

1S/C24H31P/c1-4-12-20(13-5-1)23-18-10-11-19-24(23)25(21-14-6-2-7-15-21)22-16-8-3-9-17-22/h1,4-5,10-13,18-19,21-22H,2-3,6-9,14-17H2

InChI key

LCSNDSFWVKMJCT-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
Sigma Aldrich Fine Chemicals Biosciences CyJohnPhos 97% | 247940-06-3 | MFCD01862441 | 25G
-- ₹ 55,108.80
Sigma Aldrich Fine Chemicals Biosciences CyJohnPhos | 247940-06-3 | MFCD01862441 | 5g
-- ₹ 14,500.77
Cyjohnphos
-- ₹ 445.00 - ₹ 48,861.00
247940-06-3 | 2-(Dicyclohexylphosphino)biphenyl
-- ₹ 445.00 - ₹ 51,086.00

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Description

  • General description: CyJohnPhos [(2-Biphenyl)dicyclohexylphosphine] is an air-stable, bulky and electron-rich monodentate biarylphosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions.Learn more about Buchwald Phosphine Ligands
  • Application: CyJohnPhos may be used in combination with a nickel catalyst for the Suzuki-Miyaura arylation of tertiary benzylic acetates with aryl boroxines to produce diaryl and triaryl quaternary stereocenters.[1]
  • Legal Information: Usage subject to US Patents 6307087 and 6395916.

SAFETY INFORMATION

Hazard Statements

H413

Hazard Classifications

Aquatic Chronic 4

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves