640360

Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate

Manufacturer: Sigma Aldrich

CAS Number: 32679-02-0

Synonym(S): [Rh(cod)(MeCN)2]BF4

Select a Size

Pack Size SKU Availability Price
1 G 640360-1-G In Stock ₹ 23,842.80
5 G 640360-5-G In Stock ₹ 1,13,197.80

640360 - 1 G

₹ 23,842.80

In Stock

Quantity

1

Base Price: ₹ 23,842.80

GST (18%): ₹ 4,291.704

Total Price: ₹ 28,134.504

form

solid

Quality Level

100

reaction suitability

core: rhodiumreagent type: catalyst

SMILES string

[Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1

InChI

1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;;

InChI key

KSMAFOANQHYEJG-SUESZSCISA-N

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Description

  • Application: Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate [Rh(cod)(MeCN)2]BF4 may be used as a catalyst for the rhodium(I)-catalyzed silylation of aryl iodides and bromides with tetraethoxysilanes to form aryl silanes such as (4-bromophenyl)triethoxysilane and 4-(triethoxysilyl)acetophenone.[1]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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form:
solid

Quality Level:
100

reaction suitability:
core: rhodiumreagent type: catalyst

SMILES string:
[Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1

InChI:
1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;;

InChI key:
KSMAFOANQHYEJG-SUESZSCISA-N

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CC1(C)OB(OC1(C)C)c2ccc(N)nc2

InChI:
1S/C11H17BN2O2/c1-10(2)11(3,4)16-12(15-10)8-5-6-9(13)14-7-8/h5-7H,1-4H3,(H2,13,14)

InChI key:
YFTAUNOLAHRUIE-UHFFFAOYSA-N

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WIHHVKUARKTSBU-UHFFFAOYSA-N

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