65671

(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine

≥97%

Manufacturer: Sigma Aldrich

CAS Number: 387868-06-6

Synonym(S): (1S)-1-[(1R)-1-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene, Walphos SL-W001-2

Select a Size

Pack Size SKU Availability Price
100 MG 65671-100-MG In Stock ₹ 7,209.45
500 MG 65671-500-MG In Stock ₹ 34,412.68
5 G 65671-5-G In Stock ₹ 2,61,293.85
50 G 65671-50-G In Stock ₹ 11,23,396.85
100 G 65671-100-G In Stock ₹ 18,87,273.80

65671 - 100 MG

₹ 7,209.45

In Stock

Quantity

1

Base Price: ₹ 7,209.45

GST (18%): ₹ 1,297.701

Total Price: ₹ 8,507.151

Quality Level

100

Assay

≥97%

optical purity

ee: ≥99%

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F

InChI

1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m0../s1

InChI key

LKNKYBWIZNAXBY-WLOLSGMKSA-N

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Description

  • General description: The product is an air-stable and non-hygroscopic Solvias chiral phosphine ligand.
  • Application: Walphos SL-W001-2, in the presence of a ruthenium catalyst may be used as a ligand in the following processes: Asymmetric hydrogenation of IPCA-D, a cinnamic acid derivative.[1]Addition of 3,5-difluorophenylketimine to 4-methoxyphenylboronic acid to form the corresponding tertiary substituted cyclic sulfamate derivative with high enantioselctivity.2[2]
  • Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
  • Other Notes: sold in collaboration with Solvias AG

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

Assay:
≥97%

optical purity:
ee: ≥99%

SMILES string:
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F

InChI:
1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m0../s1

InChI key:
LKNKYBWIZNAXBY-WLOLSGMKSA-N

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