664073

(S)-(+)-2,3,7,7a-Tetrahydro-7a-methyl-1H-indene-1,5(6H)-dione

97%

Manufacturer: Sigma Aldrich

CAS Number: 17553-86-5

Synonym(S): (+)-5,6,7,8-Tetrahydro-8-methylindan-1,5-dione, (+)-7,7a-Dihydro-7α, β-methyl-1,5(6H)-indandione, (S)-(+)-Hajos-Parrish diketone, (S)-Hajos dione, (S)-Hajos ketone, (S)-Hajos-Wiechert ketone

Select a Size

Pack Size SKU Availability Price
1 G 664073-1-G In Stock ₹ 5,899.63

664073 - 1 G

₹ 5,899.63

In Stock

Quantity

1

Base Price: ₹ 5,899.63

GST (18%): ₹ 1,061.933

Total Price: ₹ 6,961.563

Quality Level

100

Assay

97%

form

solid

mp

57-64 °C

SMILES string

C[C@]12CCC(=O)C=C1CCC2=O

InChI

1S/C10H12O2/c1-10-5-4-8(11)6-7(10)2-3-9(10)12/h6H,2-5H2,1H3/t10-/m0/s1

InChI key

FNYAZSZTENLTRT-JTQLQIEISA-N

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Description

  • Application: (S)-(+)-Hajos-Parrish diketone can be used as a reactant in: The total synthesis of steroidal alkaloids cortistatins.[1] The stereoselective preparation of hydroanthracenol and related polycyclic compounds via Ti(Oi-Pr)4-promoted photoenolization Diels-Alder reaction.[2] The synthesis of γ,γ-disubstituted allyldiboron compounds by reacting with allylic 1,1-diboronate reagents via Cu-catalyzed borylation and 1,2-addition reaction.[3]

SAFETY INFORMATION

Pictograms

GHS06

Signal Word

Danger

Hazard Statements

H301,H315,H317,H319,H335

Precautionary Statements

P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves