669032

PEPPSI™-IPr catalyst

98%, Umicore

Manufacturer: Sigma Aldrich

CAS Number: 905459-27-0

Synonym(S): [1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride

Select a Size

Pack Size SKU Availability Price
1 G 669032-1-G In Stock ₹ 22,144.50
5 G 669032-5-G In Stock ₹ 70,351.80
50 G 669032-50-G In Stock ₹ 2,58,474.60

669032 - 1 G

₹ 22,144.50

In Stock

Quantity

1

Base Price: ₹ 22,144.50

GST (18%): ₹ 3,986.01

Total Price: ₹ 26,130.51

Quality Level

200

Assay

98%

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

manufacturer/tradename

Umicore

mp

230 °C

SMILES string

Cl[Pd]Cl.Clc1cccnc1.CC(C)c2cccc(C(C)C)c2N3CN(C=C3)c4c(cccc4C(C)C)C(C)C

InChI

1S/C27H38N2.C5H4ClN.2ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;6-5-2-1-3-7-4-5;;;/h9-16,18-21H,17H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2

InChI key

BLDKGTGQENJFON-UHFFFAOYSA-L

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Description

  • General description: PEPPSI™-IPr catalyst widely used in carbonylative cross-coupling reactions.[1]
  • Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions
  • Legal Information: Product of UmicoreThis product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.comPatented, U.S. Pat. No. 7,250,510. Sold under an exclusive license from Total Synthesis Ltd.

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332

Precautionary Statements

P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Quality Level:
200

Assay:
98%

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

manufacturer/tradename:
Umicore

mp:
230 °C

SMILES string:
Cl[Pd]Cl.Clc1cccnc1.CC(C)c2cccc(C(C)C)c2N3CN(C=C3)c4c(cccc4C(C)C)C(C)C

InChI:
1S/C27H38N2.C5H4ClN.2ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;6-5-2-1-3-7-4-5;;;/h9-16,18-21H,17H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2

InChI key:
BLDKGTGQENJFON-UHFFFAOYSA-L

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InChI:
1S/C3H3F3O2/c4-3(5,6)1-8-2-7/h2H,1H2

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CAFROQYMUICGNO-UHFFFAOYSA-N

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1S/C11H16O2S/c1-3-11(4-2)7-12-9-5-14-6-10(9)13-8-11/h5-6H,3-4,7-8H2,1-2H3

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HMKHKPKUPVRLOW-UHFFFAOYSA-N

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OC(C#Cc1ccccc1)c2ccccc2

InChI:
1S/C15H12O/c16-15(14-9-5-2-6-10-14)12-11-13-7-3-1-4-8-13/h1-10,15-16H

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DZZWMODRWHHWFR-UHFFFAOYSA-N