678538

(−)-Ipc2B(allyl)borane solution

1 M in pentane

Manufacturer: Sigma Aldrich

CAS Number: 85116-38-7

Synonym(S): (-)-Ipc2B(allyl) solution, (−)-B-Allyldiisopinocampheylborane solution

Select a Size

Pack Size SKU Availability Price
25 ML 678538-25-ML In Stock ₹ 20,329.35

678538 - 25 ML

₹ 20,329.35

In Stock

Quantity

1

Base Price: ₹ 20,329.35

GST (18%): ₹ 3,659.283

Total Price: ₹ 23,988.633

optical activity

[α]20/D −35 to ±5°, c = 1

Quality Level

100

concentration

1 M in pentane

bp

35-36 °C

density

0.638 g/mL at 25 °C

storage temp.

−20°C

SMILES string

C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B(CC=C)[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C

InChI

1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m1/s1

InChI key

ZIXZBDJFGUIKJS-RLEROFIGSA-N

Other Options

Image Product Name Manufacturer Price Range
50-186-9008
Sigma Aldrich Fine Chemicals Biosciences (-)-Ipc2B(allyl)borane solution 1 M in pentane | 85116-38-7 | 25ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 38,675.69
AH59653
85116-38-7 | (-)-IPC2B(ALLYL), 1M IN PENTANE
A2B Chem --

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Description

  • Application: This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.[1][2]
  • Other Notes: Material may become hazy upon cooler storage, this will not affect use

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS07,GHS09

Signal Word

Danger

Hazard Statements

H224,H304,H315,H319,H335,H336,H411

Precautionary Statements

P210 - P233 - P273 - P301 + P310 - P331 - P403 + P233

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

678538

1 M in pentane...


optical activity:
[α]20/D −35 to ±5°, c = 1

Quality Level:
100

concentration:
1 M in pentane

bp:
35-36 °C

density:
0.638 g/mL at 25 °C

storage temp.:
−20°C

SMILES string:
C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B(CC=C)[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C

InChI:
1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m1/s1

InChI key:
ZIXZBDJFGUIKJS-RLEROFIGSA-N

Img

Sigma Aldrich

678562

kanata purity...


optical activity:
[α]22/D +170, c = 1 in chloroform

Quality Level:
100

concentration:
__

bp:
__

density:
__

storage temp.:
__

SMILES string:
C[C@H]1CC[C@H](C)P1c2ccccc2P3(=O)[C@@H](C)CC[C@@H]3C

InChI:
1S/C18H28OP2/c1-13-9-10-14(2)20(13)17-7-5-6-8-18(17)21(19)15(3)11-12-16(21)4/h5-8,13-16H,9-12H2,1-4H3/t13-,14-,15-,16-/m0/s1

InChI key:
ORZVYNTUPREFTI-VGWMRTNUSA-N

Img

Sigma Aldrich

678600

95%...


optical activity:
__

Quality Level:
100

concentration:
__

bp:
__

density:
__

storage temp.:
__

SMILES string:
Brc1nc2ccccc2s1

InChI:
1S/C7H4BrNS/c8-7-9-5-3-1-2-4-6(5)10-7/h1-4H

InChI key:
DRLMMVPCYXFPEP-UHFFFAOYSA-N

Img

Supelco

67861

analytical standard...


optical activity:
__

Quality Level:
__

concentration:
__

bp:
__

density:
__

storage temp.:
__

SMILES string:
OC(Cc1ccc(O)cc1)C(O)=O

InChI:
1S/C9H10O4/c10-7-3-1-6(2-4-7)5-8(11)9(12)13/h1-4,8,10-11H,5H2,(H,12,13)

InChI key:
JVGVDSSUAVXRDY-UHFFFAOYSA-N