684341

(S)-(–)-5-(2-Pyrrolidinyl)-1H-tetrazole

96%

Manufacturer: Sigma Aldrich

CAS Number: 33878-70-5

Synonym(S): (S)-(–)-2-Tetrazol-5-ylpyrrolidine, Proline Tetrazole Catalyst

Select a Size

Pack Size SKU Availability Price
100 MG 684341-100-MG In Stock ₹ 5,629.00
500 MG 684341-500-MG In Stock ₹ 15,306.55

684341 - 100 MG

₹ 5,629.00

In Stock

Quantity

1

Base Price: ₹ 5,629.00

GST (18%): ₹ 1,013.22

Total Price: ₹ 6,642.22

Quality Level

100

Assay

96%

form

solid

optical activity

[α]20/D -9.0°, c = 1 in methanol

mp

253-258 °C

SMILES string

C1CN[C@@H](C1)c2nnn[nH]2

InChI

1S/C5H9N5/c1-2-4(6-3-1)5-7-9-10-8-5/h4,6H,1-3H2,(H,7,8,9,10)/t4-/m0/s1

InChI key

XUHYQIQIENDJER-BYPYZUCNSA-N

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Description

  • Application: (S)-(−)-5-(2-Pyrrolidinyl)-1H-tetrazole can be used as an organocatalyst: To prepare enantioselective chiral 1,2-oxazines from achiral ketones via an intramolecular Wittig reaction.[1]To synthesize diastereoselective Michael addition products by addition of aliphatic aldehydes to β-nitrostyrene.[2]In the direct asymmetric α-fluorination of linear and branched aldehydes using N-fluorobenzenesulfonamide as the fluorinating agent.[3]

SAFETY INFORMATION

Pictograms

GHS06

Signal Word

Danger

Hazard Statements

H301,H315,H319,H335

Precautionary Statements

P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves