685062

(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer

Manufacturer: Sigma Aldrich

CAS Number: 12148-71-9

Synonym(S): [Ir(OMe)(1,5-cod)]2, Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)

Select a Size

Pack Size SKU Availability Price
250 MG 685062-250-MG In Stock ₹ 8,125.20
1 G 685062-1-G In Stock ₹ 27,080.00
25 G 685062-25-G In Stock ₹ 3,34,398.60

685062 - 250 MG

₹ 8,125.20

In Stock

Quantity

1

Base Price: ₹ 8,125.20

GST (18%): ₹ 1,462.536

Total Price: ₹ 9,587.736

form

crystals

Quality Level

100

reaction suitability

core: iridiumreagent type: catalystreaction type: C-H Activation

mp

154-179 °C (D)

storage temp.

−20°C

SMILES string

C[O+]1[Ir-]2[O+](C)[Ir-]12.C3CC=CCCC=C3.C4CC=CCCC=C4

InChI

1S/2C8H12.2CH3O.2Ir/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*+1;2*-1/b2*2-1-,8-7-;;;;

InChI key

BGWIAAATAAWGOI-MIXQCLKLSA-N

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Description

  • Application: Catalyst for:Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymeraseBorylation/Suzuki-Miyaura couplingMetalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiarylsTetraborylation reactionsHighly regio- and enantioselective asymmetric hydroborationOrtho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Sigma Aldrich

685062

--


form:
crystals

Quality Level:
100

reaction suitability:
core: iridiumreagent type: catalystreaction type: C-H Activation

mp:
154-179 °C (D)

storage temp.:
−20°C

SMILES string:
C[O+]1[Ir-]2[O+](C)[Ir-]12.C3CC=CCCC=C3.C4CC=CCCC=C4

InChI:
1S/2C8H12.2CH3O.2Ir/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*+1;2*-1/b2*2-1-,8-7-;;;;

InChI key:
BGWIAAATAAWGOI-MIXQCLKLSA-N

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Sigma Aldrich

685194

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form:
solid

Quality Level:
100

reaction suitability:
__

mp:
287-305 °C

storage temp.:
__

SMILES string:
Cc1cc(ccc1B(O)O)C#N

InChI:
1S/C8H8BNO2/c1-6-4-7(5-10)2-3-8(6)9(11)12/h2-4,11-12H,1H3

InChI key:
RGCVYEOTYJCNOS-UHFFFAOYSA-N

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Quality Level:
100

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mp:
40-44 °C

storage temp.:
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SMILES string:
Nc1cc(Cl)ccc1I

InChI:
1S/C6H5ClIN/c7-4-1-2-5(8)6(9)3-4/h1-3H,9H2

InChI key:
FEOMAFDDLHSVMO-UHFFFAOYSA-N

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crystals

Quality Level:
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reaction suitability:
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mp:
85-89 °C

storage temp.:
2-8°C

SMILES string:
Fc1cnccc1I

InChI:
1S/C5H3FIN/c6-4-3-8-2-1-5(4)7/h1-3H

InChI key:
MSLUTDVOKZOXTA-UHFFFAOYSA-N