688495
(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline
97%
Manufacturer: Sigma Aldrich
CAS Number: 148461-16-9
Synonym(S): (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 500 MG | 688495-500-MG | In Stock | ₹ 39,197.33 |
688495 - 500 MG
In Stock
Quantity
1
Base Price: ₹ 39,197.33
GST (18%): ₹ 7,055.519
Total Price: ₹ 46,252.849
Quality Level
100
Assay
97%
form
solid
optical activity
[α]22/D -57.0°, c = 1 in chloroform
mp
111-116 °C
storage temp.
−20°C
SMILES string
CC(C)(C)[C@@H]1N=C(C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4)OC1
InChI
1S/C25H26NOP/c1-25(2,3)23-18-27-24(26-23)21-16-10-11-17-22(21)28(19-12-6-4-7-13-19)20-14-8-5-9-15-20/h4-17,23H,18H2,1-3H3/t23-/m1/s1
InChI key
DMOLTNKQLUAXPI-HSZRJFAPSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97% | 148461-16-9 | MFCD09998277 | 500MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 43,840.94 | |
 | (S)-4-(tert-Butyl)-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole | Aaron Chemicals LLC | ₹ 1,283.40 - ₹ 37,047.48 | |
 | (S)-t-BuPHOX | ChemScene | ₹ 2,652.36 - ₹ 76,062.84 | |
 | 148461-16-9 | (S)-4-tert-Butyl-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole | A2B Chem | ₹ 1,882.32 - ₹ 1,12,596.96 |
Related Products
Description
- General description: The product is a phosphinooxazoline (PHOX) ligand introduced by Pfaltz and coworkers. These non-symmetrical modular P,N-ligands are particularly useful in cases where double bond migration leads to undesired products or mixtures of isomers.[1]
- Application: (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline can be used as a ligand for enantioselective Heck reaction without any C=C double bond migration byproduct. It can also be used in a rhodium(I)-catalyzed enantioselective desymmetrization reaction of meso-3,5-dimethyl glutaric anhydride, to form substituted syn-deoxypolypropionate fragments in a single transformation.[1]
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 97%
form: solid
optical activity: [α]22/D -57.0°, c = 1 in chloroform
mp: 111-116 °C
storage temp.: −20°C
SMILES string: CC(C)(C)[C@@H]1N=C(C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4)OC1
InChI: 1S/C25H26NOP/c1-25(2,3)23-18-27-24(26-23)21-16-10-11-17-22(21)28(19-12-6-4-7-13-19)20-14-8-5-9-15-20/h4-17,23H,18H2,1-3H3/t23-/m1/s1
InChI key: DMOLTNKQLUAXPI-HSZRJFAPSA-N
Quality Level:
100
Assay:
97%
form:
solid
optical activity:
[α]22/D -57.0°, c = 1 in chloroform
mp:
111-116 °C
storage temp.:
−20°C
SMILES string:
CC(C)(C)[C@@H]1N=C(C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4)OC1
InChI:
1S/C25H26NOP/c1-25(2,3)23-18-27-24(26-23)21-16-10-11-17-22(21)28(19-12-6-4-7-13-19)20-14-8-5-9-15-20/h4-17,23H,18H2,1-3H3/t23-/m1/s1
InChI key:
DMOLTNKQLUAXPI-HSZRJFAPSA-N
Quality Level: 100
Assay: 99.998% trace metals basis
form: liquid
optical activity: __
mp: −70 °C (lit.)
storage temp.: __
SMILES string: Cl[Si](Cl)(Cl)Cl
InChI: __
InChI key: __
Quality Level:
100
Assay:
99.998% trace metals basis
form:
liquid
optical activity:
__
mp:
−70 °C (lit.)
storage temp.:
__
SMILES string:
Cl[Si](Cl)(Cl)Cl
InChI:
__
InChI key:
__
Quality Level: 100
Assay: 99.998% trace metals basis
form: liquid
optical activity: __
mp: −70 °C (lit.)
storage temp.: __
SMILES string: Cl[Si](Cl)(Cl)Cl
InChI: __
InChI key: __
Quality Level:
100
Assay:
99.998% trace metals basis
form:
liquid
optical activity:
__
mp:
−70 °C (lit.)
storage temp.:
__
SMILES string:
Cl[Si](Cl)(Cl)Cl
InChI:
__
InChI key:
__
Quality Level: 100
Assay: 97%
form: solid
optical activity: [α]22/D −69.0, c = 1 in chloroform
mp: 134-138 °C
storage temp.: −20°C
SMILES string: Cc1ccccc1P(c2ccccc2C)c3ccccc3C4=N[C@H](CO4)C(C)(C)C
InChI: 1S/C27H30NOP/c1-19-12-6-9-15-22(19)30(23-16-10-7-13-20(23)2)24-17-11-8-14-21(24)26-28-25(18-29-26)27(3,4)5/h6-17,25H,18H2,1-5H3/t25-/m1/s1
InChI key: PWDWTBOBIGNWSX-RUZDIDTESA-N
Quality Level:
100
Assay:
97%
form:
solid
optical activity:
[α]22/D −69.0, c = 1 in chloroform
mp:
134-138 °C
storage temp.:
−20°C
SMILES string:
Cc1ccccc1P(c2ccccc2C)c3ccccc3C4=N[C@H](CO4)C(C)(C)C
InChI:
1S/C27H30NOP/c1-19-12-6-9-15-22(19)30(23-16-10-7-13-20(23)2)24-17-11-8-14-21(24)26-28-25(18-29-26)27(3,4)5/h6-17,25H,18H2,1-5H3/t25-/m1/s1
InChI key:
PWDWTBOBIGNWSX-RUZDIDTESA-N