(R)-Tol-BINAP
Manufacturer: Sigma Aldrich
CAS Number: 99646-28-3
Synonym(S): (R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 500 MG | 693049-500-MG | In Stock | ₹ 6,343.45 |
693049 - 500 MG
In Stock
Quantity
1
Base Price: ₹ 6,343.45
GST (18%): ₹ 1,141.821
Total Price: ₹ 7,485.271
form
solid
Quality Level
100
optical activity
[α]20/D +162°, c = 0.5 in benzene
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Cross Couplings
mp
254-258 °C
functional group
phosphine
SMILES string
Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8
InChI
1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3
InChI key
IOPQYDKQISFMJI-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | 99646-28-3 | Phosphine, (1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)- | A2B Chem | ₹ 1,368.96 - ₹ 31,400.52 |
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Description
- General description: BINAP is based on a bis naphthalene backbone with different phosphine derivatives. 2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl (p-Tol-BINAP)·AgF complex catalyzed asymmetric Mukaiyama-type aldol reaction is reported.[1]
- Application: Takasago Ligands and Complexes for Asymmetric Reactions
- Legal Information: Sold in collaboration with Takasago for research purposes only.
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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form: solid
Quality Level: 100
optical activity: [α]20/D +162°, c = 0.5 in benzene
reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Cross Couplings
mp: 254-258 °C
functional group: phosphine
SMILES string: Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8
InChI: 1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3
InChI key: IOPQYDKQISFMJI-UHFFFAOYSA-N
form: crystals
Quality Level: 100
optical activity: [α]20/D -222, c = 0.5 in benzene
reaction suitability: __
mp: 238-240 °C (lit.)
functional group: __
SMILES string: __
InChI: 1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
InChI key: MUALRAIOVNYAIW-UHFFFAOYSA-N
form: crystals
Quality Level: 100
optical activity: [α]20/D +222°, c = 0.5% in benzene
reaction suitability: __
mp: 239-241 °C (lit.)
functional group: __
SMILES string: c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
InChI: 1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
InChI key: MUALRAIOVNYAIW-UHFFFAOYSA-N
