695459

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

97%

Manufacturer: Sigma Aldrich

CAS Number: 97739-46-3

Synonym(S): 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane, meCgPPh

Select a Size

Pack Size SKU Availability Price
500 MG 695459-500-MG In Stock ₹ 11,138.93
2 G 695459-2-G In Stock ₹ 32,074.48

695459 - 500 MG

₹ 11,138.93

In Stock

Quantity

1

Base Price: ₹ 11,138.93

GST (18%): ₹ 2,005.007

Total Price: ₹ 13,143.937

Quality Level

100

Assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Cross Couplings

mp

106-111 °C

functional group

phosphine

SMILES string

CC12CC3(C)OC(C)(CC(C)(O1)P3c4ccccc4)O2

InChI

1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3

InChI key

AVVSJWUWBATQBX-UHFFFAOYSA-N

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Description

  • Application: 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:As a ligand to synthesize complexes for hydroformylation catalysis.[1][2]To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones[3] and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.[4]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable