695874

t-BuDavePhos

Manufacturer: Sigma Aldrich

CAS Number: 224311-49-3

Synonym(S): 2′-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine, t-Butyl DavePhos, 2-Di-tert-butylphosphino-2′-(N,N-dimethylamino)biphenyl, tBuDavePhos

Select a Size

Pack Size SKU Availability Price
250 MG 695874-250-MG In Stock ₹ 2,814.50
1 G 695874-1-G In Stock ₹ 9,883.23
5 G 695874-5-G In Stock ₹ 30,093.50

695874 - 250 MG

₹ 2,814.50

In Stock

Quantity

1

Base Price: ₹ 2,814.50

GST (18%): ₹ 506.61

Total Price: ₹ 3,321.11

form

solid

Quality Level

100

reaction suitability

reagent type: ligandreaction type: Arylationsreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: C-X Bond Formation

mp

114-118 °C

functional group

phosphine

SMILES string

CN(C)c1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C

InChI

1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3

InChI key

PHLPNEHPCYZBNZ-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-175-1622
Sigma Aldrich Fine Chemicals Biosciences t-BuDavePhos | 224311-49-3 | MFCD03426986 | 5G
Sigma Aldrich Fine Chemicals Biosciences ₹ 46,407.74
50-175-1620
Sigma Aldrich Fine Chemicals Biosciences t-BuDavePhos | 224311-49-3 | MFCD03426986 | 1G
Sigma Aldrich Fine Chemicals Biosciences ₹ 20,123.71
50-175-1621
Sigma Aldrich Fine Chemicals Biosciences t-BuDavePhos | 224311-49-3 | MFCD03426986 | 250MG
Sigma Aldrich Fine Chemicals Biosciences ₹ 5,869.42
AD23777
224311-49-3 | 2-(Di-tert-butylphosphino)-2'-(n,n-dimethylamino)biphenyl
A2B Chem ₹ 684.48 - ₹ 13,261.80

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Description

  • Application: Learn more about Buchwald Phosphine LigandsDialkylbiaryl phosphine ligand often used for Pd-catalyzed reactions in a range of contexts.

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335,H413

Precautionary Statements

P273 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Sigma Aldrich

695874

--


form:
solid

Quality Level:
100

reaction suitability:
reagent type: ligandreaction type: Arylationsreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: C-X Bond Formation

mp:
114-118 °C

functional group:
phosphine

SMILES string:
CN(C)c1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C

InChI:
1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3

InChI key:
PHLPNEHPCYZBNZ-UHFFFAOYSA-N

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Sigma Aldrich

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powder

Quality Level:
100

reaction suitability:
reaction type: Cross Couplingsreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: C-C Bond Formation

mp:
122-126 °C

functional group:
phosphine

SMILES string:
CN(C)c1ccccc1-c2ccccc2P(c3ccccc3)c4ccccc4

InChI:
1S/C26H24NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h3-20H,1-2H3

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JGFXUYLYPITYGR-UHFFFAOYSA-N

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InChI key:
KAKZBPTYRLMSJV-UHFFFAOYSA-N

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SMILES string:
CC1=CC(=O)Oc2cc(O[C@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)ccc12

InChI:
1S/C16H18O8/c1-7-4-12(18)23-10-5-8(2-3-9(7)10)22-16-15(21)14(20)13(19)11(6-17)24-16/h2-5,11,13-17,19-21H,6H2,1H3/t11-,13-,14+,15-,16+/m1/s1

InChI key:
YUDPTGPSBJVHCN-JZYAIQKZSA-N